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dc.contributor.author | El Hadad, Amir A. | - |
dc.contributor.author | Carbonell, Diógenes | - |
dc.contributor.author | Barranco, Violeta | - |
dc.contributor.author | Jiménez-Morales, A. | - |
dc.contributor.author | Casal, Blanca | - |
dc.contributor.author | Galván Sierra, Juan Carlos | - |
dc.date.accessioned | 2012-06-12T10:55:57Z | - |
dc.date.available | 2012-06-12T10:55:57Z | - |
dc.date.issued | 2011-09 | - |
dc.identifier.citation | Colloid & Polymer Science 289 (17-18) : 1875-1883 (2011) | es_ES |
dc.identifier.issn | 0303-402X | - |
dc.identifier.uri | http://hdl.handle.net/10261/51377 | - |
dc.description.abstract | Organic–inorganic hybrid materials suitable for the development of sol–gel coatings for metallic surfaces were prepared by hydrolysis and condensation of γ- methacryloxypropyltrimethoxysilane (MAPTMS) and tetramethyl orthosilicate (TMOS). The hydrolysis of MAPTMS/ TMOS was carried out in an ethanol/water solution. The prehydrolysis stage of MAPTMS/TMOS system was monitored by Fourier transform infrared spectroscopy (FTIR) and liquid-state 29Si and 13C nuclear magnetic resonance (29Si and 13C NMR). FTIR analysis indicated that the hydrolysis of MAPTMS/TMOS was accomplished as far as the (SiOMe) band corresponding to unhydrolyzed silane disappeared. The concentration of the alkoxy groups and the extent of self-condensation of mono-, di-, and trisubstituted siloxanes (T species) in the sol were estimated by using liquid-state 29Si NMR spectroscopy. The hydrolysis of the prepared sol was also evaluated by liquid-state 13C NMR spectroscopy. The results indicated that under the adopted synthesis strategy conditions, the hydrolysis process requires 4 h to be completed. | es_ES |
dc.description.sponsorship | This work has been supported by the Ministry of Science and Innovation of Spain (Projects MAT2006-04486 and MAT2009-13530) and the Regional Community of Madrid (Project 2009/MAT-1585). AA El hadad acknowledges a predoctoral contract JAE financed by CSIC, and VB acknowledges a Ramon y Cajal researcher contract financed by CSIC-MICINN. | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | Springer Nature | es_ES |
dc.rights | openAccess | es_ES |
dc.subject | Sol–gel | es_ES |
dc.subject | Silica | es_ES |
dc.subject | Organic–inorganic materials | es_ES |
dc.subject | Organopolysiloxane precursors | es_ES |
dc.subject | Si-29 and C-13 NMR | es_ES |
dc.subject | FTIR | es_ES |
dc.subject | Structural characterization | es_ES |
dc.title | Preparation of sol–gel hybrid materials from γ-methacryloxypropyltrimethoxysilane and tetramethyl orthosilicate: study of the hydrolysis and condensation reactions | es_ES |
dc.type | artículo | es_ES |
dc.identifier.doi | 10.1007/s00396-011-2504-y | - |
dc.description.peerreviewed | Peer reviewed | es_ES |
dc.relation.publisherversion | http://dx.doi.org/10.1007/s00396-011-2504-y | es_ES |
dc.type.coar | http://purl.org/coar/resource_type/c_6501 | es_ES |
item.cerifentitytype | Publications | - |
item.grantfulltext | open | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.fulltext | With Fulltext | - |
item.languageiso639-1 | en | - |
item.openairetype | artículo | - |
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Manuscript_J.C.Galvan.pdf | 455,81 kB | Adobe PDF | Visualizar/Abrir |
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