Please use this identifier to cite or link to this item: http://hdl.handle.net/10261/51033
Título : Iridium oxohydroxide, a significant member in the family of iridium oxides. Stoichiometry, characterization, and implications in bioelectrodes
Autor : Cruz, A. M., Abad, Llibertat, Carretero, N. M., Moral-Vico, J., Fraxedas, J., Subías, G., Casañ Pastor, Nieves
Fecha de publicación : 2012
Editor: American Chemical Society
Citación : Journal of Physical Chemistry C 116(8): 5155-5168 (2012)
Resumen: Iridium oxohydroxide thin coatings have been prepared by a dynamic oxidation electrodeposition method from complex oxalate solutions that induce template effects in the final coating at the nanoscale. The preparation method induces the formation of a oxohydroxide with reproducible stoichiometry and sponge-like quasiamorphous open structure, high ionic mobility, and significant behavior as compared with other reported iridium oxides as derived from X-ray diffraction, XPS, and TGA. Reproducible mixed valence states are also observed and a local rutile structure that allows ion exchange and facile redox changes. Rather significant is the large affinity for organic compounds observed and the behavior as substrate for cell culture, the best observed to date. Optimal cell response seems to be related to such open structure, which suggests this coating as ideal for devices implanted in the nervous system. © 2012 American Chemical Society.
Descripción : et al.
URI : http://hdl.handle.net/10261/51033
Identificadores: doi: 10.1021/jp212275q
issn: 1932-7447
Appears in Collections:(CIN2) Artículos
(ICMA) Artículos
(ICMAB) Artículos

Files in This Item:
File Description SizeFormat 
accesoRestringido.pdf15,38 kBAdobe PDFView/Open
Show full item record
 
CSIC SFX LinksSFX Query

Items in Digital.CSIC are protected by copyright, with all rights reserved, unless otherwise indicated.