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Título: | Compositional, structural and morphological modifications of N-rich Cu3N films induced by irradiation with Cu ions at 42 MeV |
Autor: | Gordillo, Nuria; Rivera de Mena, Antonio CSIC ORCID; González-Arrabal, Raquel CSIC ORCID | Palabras clave: | Semiconductors Surfaces, interfaces and thin films |
Fecha de publicación: | 2010 | Editor: | Institute of Physics Publishing | Citación: | Journal of Physics D - Applied Physics 43: 345301 (2010) | Resumen: | N-rich Cu3N films were irradiated with Cu at 42 MeV in the fluences range from 4 × 1011 to 1 × 1014 cm−2. The radiation-induced changes in the chemical composition, structural phases, surface morphology and optical properties have been characterized as a function of ion fluence, substrate temperature and angle of incidence of the incoming ion by means of ion-beam analysis (IBA), x-ray diffraction, atomic force microscopy, profilometry and Fourier transform infrared spectroscopy techniques. IBA methods reveal a very efficient sputtering of N whose yield (5 × 103 atom/ion) is almost independent of substrate temperature (RT-300 °C) but slightly depends on the incidence angle of the incoming ion. The Cu content remains essentially constant within the investigated fluence range. All data suggest an electronic mechanism to be responsible for the N depletion. The release of nitrogen and the formation of Cu2O and metallic Cu are discussed on the basis of existing models. | Descripción: | PACS
68.55.-a Thin film structure and morphology
78.30.Am Elemental semiconductors and insulators
68.35.B- Structure of clean surfaces (and surface reconstruction)
78.66.Li Other semiconductors
61.80.Jh Ion radiation effects
61.82.Fk Semiconductors Nuria Gordillo...et al. |
Versión del editor: | http://dx.doi.org/10.1088/0022-3727/43/34/345301 | URI: | http://hdl.handle.net/10261/48379 | DOI: | 10.1088/0022-3727/43/34/345301 | ISSN: | 0022-3727 |
Aparece en las colecciones: | (IMN-CNM) Artículos |
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Compositional_structural.pdf | 1,19 MB | Adobe PDF | Visualizar/Abrir |
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