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Title

Redox-active tetrathiafulvalene and dithiolene compounds derived from allylic 1,4-diol rearrangement products of disubstituted 1,3-dithiole derivatives

AuthorsVilela, Filipe; Luquin, Asunción; Coles, Simon J.; Hursthouse, Michael B.
KeywordsAldehydes
Metal-coordination
Rearrangement
Sulfur heterocycles
Tetrathiafulvalene
Issue Date2010
PublisherBeilstein-Institut zur Förderung der Chemischen Wissenschaften
CitationBeilstein Journal of Organic Chemistry 6: 1002-1014 (2010)
AbstractWe present a series of compounds by exploiting the unusual 1,4-aryl shift observed for electron-rich 1,3-dithiole-2-thione and tetrathiafulvalene (TTF) derivatives in the presence of perchloric acid. The mechanistic features of this rearrangement are discussed since this synthetic strategy provides an alternative route for the synthesis and functionalisation of sulfur rich compounds including redox active compounds of TTFs, and a Ni dithiolene.
Description13 páginas, 7 figuras, 2 tablas.-- This is an Open Access article under the terms of the Creative Commons Attribution License.-- et al.
Publisher version (URL)http://dx.doi.org/10.3762/bjoc.6.113
URIhttp://hdl.handle.net/10261/47860
DOI10.3762/bjoc.6.113
ISSN1860-5397
Appears in Collections:(ICMA) Artículos
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