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Growth and structure of self-assembled monolayers of a TTF derivative on Au(111)

AuthorsTrelka, Marta; Lorente, Nicolás ; Arnau, Andrés ; Martín, Nazario; Otero, Roberto; Gallego, José M. ; Miranda, Rodolfo
Issue Date2010
PublisherAmerican Chemical Society
CitationJournal of Physical Chemistry C 114(14): 6503–6510 (2010)
AbstractThe adsorption of a TTF derivative (2-[9-(1,3-dithiol-2-ylidene)anthracen-10(9H)-ylidene]-1,3-dithiole, exTTF) on Au(111) has been studied by a combination of scanning tunneling microscopy, photoelectron spectroscopy, and theoretical calculations. The results indicate that the molecule−substrate interaction is dominated by the S−Au bonds. However, due to conformational reasons, only one of the two dithiole rings is in close contact with the surface. As a consequence, the interaction with the Au surface is much smaller (less than half) the interaction of TTF with Au(111), where the four sulfur atoms are in direct contact.
Description8 páginas, 13 figuras.-- et al.
Publisher version (URL)http://dx.doi.org/10.1021/jp911839b
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