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Title

Mono- and Diaminocarbenes from Chloroiminium and -amidinium Salts:Synthesis of Metal-Free Bis(dimethylamino)carbene

AuthorsOtto, Michael; Conejero, Salvador ; Canac, Yves; Romanenko, Vadim D.; Rudzevitch, Valentyn; Bertrand, Guy
KeywordsDiaminocarbenes
Synthesis
Carbenes
Mercury
Chloride
Dimethylamino
Issue Date6-Jan-2004
PublisherAmerican Chemical Society
CitationJournal of the American Chemical Society 126(4): 1016-1017 (2004)
AbstractBis(trimethylsilyl)mercury cleanly reacts at low temperature with chloroamidinium and -iminium chlorides, generating persistent metal-free cyclic and acyclic diaminocarbenes, as well as transient aryl-, chloro-, and hydrogenoaminocarbenes; with the latter, the corresponding olefin dimers were isolated, whereas with the former, no dimerization processes were observed.
Description2 páginas, 1 tabla, 3 esquemas.
Publisher version (URL)http://dx.doi.org/10.1021/ja0393325
URIhttp://hdl.handle.net/10261/37966
DOI10.1021/ja0393325
ISSN0002-7863
Appears in Collections:(IIQ) Artículos
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