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http://hdl.handle.net/10261/37912
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Campo DC | Valor | Lengua/Idioma |
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dc.contributor.author | Resa, Irene | - |
dc.contributor.author | Álvarez, Eleuterio | - |
dc.contributor.author | Carmona, Ernesto | - |
dc.date.accessioned | 2011-07-21T12:47:26Z | - |
dc.date.available | 2011-07-21T12:47:26Z | - |
dc.date.issued | 2007-08-27 | - |
dc.identifier.citation | Zeitschrift fur Anorganische und Allgemeine Chemie 633(11-12): 1827-1831 (2007) | es_ES |
dc.identifier.issn | 0044-2313 | - |
dc.identifier.uri | http://hdl.handle.net/10261/37912 | - |
dc.description | 5 páginas, 3 figuras, 2 tablas, 2 esquemas. | es_ES |
dc.description.abstract | Half-sandwich zinc complexes (η5-C5Me5)ZnR have been prepared for R= Me, 2; Et, 3; Mes, 4 and Ph, 5, by the conproportionation reaction of Zn(C5Me5)2 and the corresponding ZnR2 reagent. The new compounds have been fully characterized by spectroscopy and in the cases of 2 and 4 by X-ray crystallography. Since the reaction of Zn(C5Me5)2 and ZnEt2 yields 3, together with the known dizincocene Zn2(η5-C5Me5)2, the rearrangements of the related zincocenes ZnCp2′ and ZnEt2 were investigated, with the result that only the half-sandwich (η5-Cp′)ZnEt derivatives (Cp′= C5Me4SiMe3 (6); C5Me4CMe3 (7) and C5Me4H (8)) were produced. | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | Wiley-VCH | es_ES |
dc.rights | closedAccess | es_ES |
dc.subject | Zinc | es_ES |
dc.subject | Metallocenes | es_ES |
dc.subject | Sandwich complexes | es_ES |
dc.subject | Solid-state structure | es_ES |
dc.title | Synthesis and Structure of Half-Sandwich Zincocenes | es_ES |
dc.type | artículo | es_ES |
dc.identifier.doi | 10.1002/zaac.200700201 | - |
dc.description.peerreviewed | Peer reviewed | es_ES |
dc.relation.publisherversion | http://dx.doi.org/10.1002/zaac.200700201 | es_ES |
dc.type.coar | http://purl.org/coar/resource_type/c_6501 | es_ES |
item.openairetype | artículo | - |
item.grantfulltext | none | - |
item.cerifentitytype | Publications | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.fulltext | No Fulltext | - |
item.languageiso639-1 | en | - |
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