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Title: Thiodipropionate ZnII Complexes: Synthesis, DFT Studies, and X-ray Structure of [{Zn(phen)(H2O)}2(μ-tdp)2]·3H2O
Authors: Grirrane, Abdessamad, Álvarez, Eleuterio, Pastor, Antonio, Galindo, Agustín
Keywords: Zinc
Density functional calculations
Coordination modes
Thiodipropionate
X-ray diffraction
Issue Date: 11-Nov-2010
Publisher: Wiley-VCH
Abstract: The zinc thiodipropionate complex [Zn(tdp)] (1) [tdp = S(CH2CH2COO)22–] was obtained by reaction of aqueous zinc dichloride with a 1:1 mixture of Na2CO3 and thiodipropionic acid. The bonding preferences of the tdp anion were studied by DFT methods. The reaction of 1 with o-phenanthroline (phen) gave the dinuclear compound [{Zn(phen)(H2O)}2(μ-tdp)2]·3H2O (2), which was characterized by X-ray analysis.
Description: 4 páginas, 4 figuras, 2 tablas, 1 esquema.
Publisher version (URL): http://dx.doi.org/10.1002/zaac.201000145
URI: http://hdl.handle.net/10261/37911
ISSN: 0044-2313
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Citation: Zeitschrift fur Anorganische und Allgemeine Chemie 636(13-14): 2409-2412 (2010)
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