Please use this identifier to cite or link to this item:
http://hdl.handle.net/10261/37845
Share/Export:
SHARE CORE BASE | |
Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL | DATACITE | |
Title: | Synthesis of mixed cobalt–nickel oxydiacetate compounds: The X-ray characterization of [Co0.4Ni0.6(oda)(H2O)3] · 1.5H2O |
Authors: | Grirrane, Abdessamad; Pastor, Antonio; Álvarez, Eleuterio CSIC ORCID ; González, Manuel; Galindo, Agustín | Keywords: | Cobalt Nickel Oxydiacetate Coordination chemistry Crystal structures Oxides |
Issue Date: | 24-Mar-2007 | Publisher: | Elsevier | Citation: | Polyhedron 26(13): 3343-3349 (2007) | Abstract: | Mixed cobalt–nickel oxydiacetate [CoxNi1−x(oda)(H2O)3] · 1.5H2O compounds (; x = 0.3, 0.4, 0.6) were synthesized from the reaction of aqueous solutions of a mixture of nickel dichloride and cobalt dichloride with a 1:1 mixture of Na2CO3 and oxydiacetic acid, O(CH2COOH)2. In particular, compound [Co0.4Ni0.6(oda)(H2O)3] · 1.5H2O (1) was characterized by single-crystal X-ray analysis. Complex 1 is a co-crystallization of [Ni(oda)(H2O)3] · 1.5H2O and [Co(oda)(H2O)3] · 1.5H2O compounds, the latter species being a new hydrated form of cobalt oxydiacetate that shows a fac-coordination for the oda ligand. These compounds can be used for the preparation of mixed metal oxides. For instance, thermal decomposition of 1, carried out under a nitrogen atmosphere, produces essentially Co0.4Ni0.6O oxide. | Description: | 7 páginas, 4 figuras, 3 tablas, 2 esquemas. | Publisher version (URL): | http://dx.doi.org/10.1016/j.poly.2007.03.020 | URI: | http://hdl.handle.net/10261/37845 | DOI: | 10.1016/j.poly.2007.03.020 | ISSN: | 0277-5387 |
Appears in Collections: | (IIQ) Artículos |
Show full item record
CORE Recommender
SCOPUSTM
Citations
8
checked on Apr 21, 2024
WEB OF SCIENCETM
Citations
10
checked on Feb 27, 2024
Page view(s)
338
checked on Apr 23, 2024
Google ScholarTM
Check
Altmetric
Altmetric
WARNING: Items in Digital.CSIC are protected by copyright, with all rights reserved, unless otherwise indicated.