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dc.contributor.authorCámpora, Juan-
dc.contributor.authorPalma, Pilar-
dc.contributor.authorRío, Diego del-
dc.contributor.authorLópez, Jorge A.-
dc.contributor.authorÁlvarez, Eleuterio-
dc.contributor.authorConnelly, Neil G.-
dc.date.accessioned2011-07-14T13:22:28Z-
dc.date.available2011-07-14T13:22:28Z-
dc.date.issued2005-06-23-
dc.identifier.citationOrganometallics 24(15): 3624-3628 (2005)es_ES
dc.identifier.issn0276-7333-
dc.identifier.urihttp://hdl.handle.net/10261/37776-
dc.description5 páginas, 2 figuras, 2 tablas, esquemas.es_ES
dc.description.abstractA new method for the synthesis of cationic Pd(IV) complexes, based on the chemical oxidation of an anionic Pd(II) metallacycle in the presence of an additional ligand, is presented. Electrochemical analysis of these compounds reveals that the stability of the +4 oxidation state is sensitive to the electron-donor capability of the added co-ligand and to the steric features of the Tp‘ ligand.es_ES
dc.description.sponsorshipFinancial support from the DGI (Project PPQ2003-00975), the Ministerio de Educación, Cultura y Deporte (research studentship, D.d.R.), and the Junta de Andalucía is gratefully acknowledged.es_ES
dc.language.isoenges_ES
dc.publisherAmerican Chemical Societyes_ES
dc.rightsclosedAccesses_ES
dc.subjectCationic palladiumes_ES
dc.subjectSynthesises_ES
dc.subjectRedoxes_ES
dc.subjectChemical oxidationes_ES
dc.subjectAnionices_ES
dc.subjectMetallacycleses_ES
dc.titleRedox Behavior of an Organometallic Palladium(II)/Palladium(IV) System. A New Method for the Synthesis of Cationic Palladium(IV) Complexeses_ES
dc.typeartículoes_ES
dc.identifier.doi10.1021/om050216f-
dc.description.peerreviewedPeer reviewedes_ES
dc.relation.publisherversionhttp://dx.doi.org/10.1021/om050216fes_ES
dc.type.coarhttp://purl.org/coar/resource_type/c_6501es_ES
item.grantfulltextnone-
item.cerifentitytypePublications-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.languageiso639-1en-
item.fulltextNo Fulltext-
item.openairetypeartículo-
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