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Please use this identifier to cite or link to this item: http://hdl.handle.net/10261/37776
Title: Redox Behavior of an Organometallic Palladium(II)/Palladium(IV) System. A New Method for the Synthesis of Cationic Palladium(IV) Complexes
Authors: Cámpora, Juan; Palma Ramírez, Pilar; Río, Diego del; López, Jorge A.; Álvarez, Eleuterio; Connelly, Neil G.
Keywords: Cationic palladium
Chemical oxidation
Issue Date: 23-Jun-2005
Publisher: American Chemical Society
Citation: Organometallics 24(15): 3624-3628 (2005)
Abstract: A new method for the synthesis of cationic Pd(IV) complexes, based on the chemical oxidation of an anionic Pd(II) metallacycle in the presence of an additional ligand, is presented. Electrochemical analysis of these compounds reveals that the stability of the +4 oxidation state is sensitive to the electron-donor capability of the added co-ligand and to the steric features of the Tp‘ ligand.
Description: 5 páginas, 2 figuras, 2 tablas, esquemas.
Publisher version (URL): http://dx.doi.org/10.1021/om050216f
URI: http://hdl.handle.net/10261/37776
ISSN: 0276-7333
DOI: 10.1021/om050216f
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