Please use this identifier to cite or link to this item: http://hdl.handle.net/10261/37776
Share/Impact:
Title: Redox Behavior of an Organometallic Palladium(II)/Palladium(IV) System. A New Method for the Synthesis of Cationic Palladium(IV) Complexes
Authors: Cámpora, Juan, Palma Ramírez, Pilar, Río, Diego del, López, Jorge A., Álvarez, Eleuterio, Connelly, Neil G.
Keywords: Cationic palladium
Synthesis
Redox
Chemical oxidation
Anionic
Metallacycles
Issue Date: 23-Jun-2005
Publisher: American Chemical Society
Abstract: A new method for the synthesis of cationic Pd(IV) complexes, based on the chemical oxidation of an anionic Pd(II) metallacycle in the presence of an additional ligand, is presented. Electrochemical analysis of these compounds reveals that the stability of the +4 oxidation state is sensitive to the electron-donor capability of the added co-ligand and to the steric features of the Tp‘ ligand.
Description: 5 páginas, 2 figuras, 2 tablas, esquemas.
Publisher version (URL): http://dx.doi.org/10.1021/om050216f
URI: http://hdl.handle.net/10261/37776
ISSN: 0276-7333
???metadata.dc.identifier.doi???: 10.1021/om050216f
Citation: Organometallics 24(15): 3624-3628 (2005)
Appears in Collections:(IIQ) Artículos
Files in This Item:
There are no files associated with this item.
Show full item record
 
CSIC SFX LinksSFX Query


Items in Digital.CSIC are protected by copyright, with all rights reserved, unless otherwise indicated.