Please use this identifier to cite or link to this item: http://hdl.handle.net/10261/37768
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Título : Fluoride Displacement by Lithium Reagents. An Improved Method for the Synthesis of Nickel Hydroxo, Alkoxo, and Amido Complexes
Autor : Cámpora, Juan, Matas, Inmaculada, Palma Ramírez, Pilar, Graiff, Claudia, Tiripicchio, Antonio
Palabras clave : Fluoride displacement
Lithium reagents
Synthesis
Nickel hydroxo
Alkoxo
Amido
β-hydrogen
Mononuclear Ni(II)
Fecha de publicación : 6-May-2005
Editor: American Chemical Society
Resumen: The complex Ni(Me)(F)(dippe) undergoes clean fluoride displacement reactions with Li(OH), Li(OtBu), and Li(NC4H8), affording the corresponding cis hydroxo, alkoxo, and amido methyl derivatives. These compounds display limited thermal stability and decompose by β-hydrogen elimination or disproportionation processes under mild conditions.
Descripción : 4 páginas, 2 figuras, 2 esquemas.
Versión del editor: http://dx.doi.org/10.1021/om0489709
URI : http://hdl.handle.net/10261/37768
ISSN: 0276-7333
DOI: 10.1021/om0489709
Citación : Organometallics 24(12): 2827-2830 (2005)
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