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Please use this identifier to cite or link to this item: http://hdl.handle.net/10261/37768
Title: Fluoride Displacement by Lithium Reagents. An Improved Method for the Synthesis of Nickel Hydroxo, Alkoxo, and Amido Complexes
Authors: Cámpora, Juan ; Matas, Inmaculada ; Palma, Pilar ; Graiff, Claudia; Tiripicchio, Antonio
Keywords: Fluoride displacement
Lithium reagents
Nickel hydroxo
Mononuclear Ni(II)
Issue Date: 6-May-2005
Publisher: American Chemical Society
Citation: Organometallics 24(12): 2827-2830 (2005)
Abstract: The complex Ni(Me)(F)(dippe) undergoes clean fluoride displacement reactions with Li(OH), Li(OtBu), and Li(NC4H8), affording the corresponding cis hydroxo, alkoxo, and amido methyl derivatives. These compounds display limited thermal stability and decompose by β-hydrogen elimination or disproportionation processes under mild conditions.
Description: 4 páginas, 2 figuras, 2 esquemas.
Publisher version (URL): http://dx.doi.org/10.1021/om0489709
URI: http://hdl.handle.net/10261/37768
DOI: 10.1021/om0489709
ISSN: 0276-7333
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