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Please use this identifier to cite or link to this item: http://hdl.handle.net/10261/37756
Title: Self-Addition of Metallacyclic Nickel Enolate Complexes Stabilized by Monodentate Phosphine Ligands
Authors: Cámpora, Juan; Matas, Inmaculada; Maya, Celia; Palma, Pilar; Álvarez, Eleuterio
Keywords: Self-addition
Nickel enolate
Monodentate ligands
Metallacyclic enolate complexes
Aldol reaction
Issue Date: 17-May-2006
Publisher: American Chemical Society
Citation: Organometallics 25(13): 3124-3129 (2006)
Abstract: In contrast with their stable counterparts bearing the chelating diphosphines, the nickelacyclic O-enolate complexes stabilized by monodentate ligands (R = H, Me, L = PMe3; R = H, L = PMe2Ph ) undergo an unusual self-addition process leading to dinuclear alkoxo-hydroxo derivatives. The α-substituted enolate complexes (R = Me) are less prone to undergo this transformation, and the corresponding nickelacycles with L = PMe3 or PMe2Ph can be isolated in pure form.
Description: 6 páginas, 4 figuras, esquemas.
Publisher version (URL): http://dx.doi.org/10.1021/om060183j
URI: http://hdl.handle.net/10261/37756
DOI: 10.1021/om060183j
ISSN: 0276-7333
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