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| Title: | Decomposition of Methylnickel(II) Amido, Alkoxo, and Alkyl Complexes by β-Hydrogen Elimination: A Comparative Study |
Authors: | Matas, Inmaculada CSIC; Cámpora, Juan CSIC ORCID; Palma, Pilar CSIC ORCID; Álvarez, Eleuterio CSIC ORCID | Keywords: | Amido Alkoxo Alkyl β-hydrogen Methane Methylnickel Thermolysis |
Issue Date: | 28-Oct-2009 | Publisher: | American Chemical Society | Citation: | Organometallics 28(22): 6515-6523 (2009) | Abstract: | Thermal decomposition of structurally related amido, alkoxo, and alkyl complexes of type [Ni(Me)(EC(H)RR′)(dippe)] (EC(H)RR′ = cyclo-NC4H8 (pyrrolidino), N(CH2Ph)2, OCH2Ph, OCH(Me)Ph, and CH2CH2Ph) takes place through formally analogous processes involving β-hydrogen elimination and reductive elimination of methane, cleanly affording corresponding Ni(0) imine, aldehyde, ketone, and olefin complexes, [Ni(η2-E═CRR′)(dippe)]. Kinetic studies on these decomposition reactions show that, in spite of their similarity, they involve substantial mechanistic differences. | Description: | 9 páginas, 7 figuras, 6 esquemas. | Publisher version (URL): | http://dx.doi.org/10.1021/om900400s | URI: | http://hdl.handle.net/10261/37705 | DOI: | 10.1021/om900400s | ISSN: | 0276-7333 |
| Appears in Collections: | (IIQ) Artículos |
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