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Please use this identifier to cite or link to this item: http://hdl.handle.net/10261/37705
Title: Decomposition of Methylnickel(II) Amido, Alkoxo, and Alkyl Complexes by β-Hydrogen Elimination: A Comparative Study
Authors: Matas, Inmaculada; Cámpora, Juan; Palma, Pilar; Álvarez, Eleuterio
Keywords: Amido
Issue Date: 28-Oct-2009
Publisher: American Chemical Society
Citation: Organometallics 28(22): 6515-6523 (2009)
Abstract: Thermal decomposition of structurally related amido, alkoxo, and alkyl complexes of type [Ni(Me)(EC(H)RR′)(dippe)] (EC(H)RR′ = cyclo-NC4H8 (pyrrolidino), N(CH2Ph)2, OCH2Ph, OCH(Me)Ph, and CH2CH2Ph) takes place through formally analogous processes involving β-hydrogen elimination and reductive elimination of methane, cleanly affording corresponding Ni(0) imine, aldehyde, ketone, and olefin complexes, [Ni(η2-E═CRR′)(dippe)]. Kinetic studies on these decomposition reactions show that, in spite of their similarity, they involve substantial mechanistic differences.
Description: 9 páginas, 7 figuras, 6 esquemas.
Publisher version (URL): http://dx.doi.org/10.1021/om900400s
URI: http://hdl.handle.net/10261/37705
DOI: 10.1021/om900400s
ISSN: 0276-7333
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