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Title

Decomposition of Methylnickel(II) Amido, Alkoxo, and Alkyl Complexes by β-Hydrogen Elimination: A Comparative Study

AuthorsMatas, Inmaculada ; Cámpora, Juan ; Palma, Pilar ; Álvarez, Eleuterio
KeywordsAmido
Alkoxo
Alkyl
β-hydrogen
Methane
Methylnickel
Thermolysis
Issue Date28-Oct-2009
PublisherAmerican Chemical Society
CitationOrganometallics 28(22): 6515-6523 (2009)
AbstractThermal decomposition of structurally related amido, alkoxo, and alkyl complexes of type [Ni(Me)(EC(H)RR′)(dippe)] (EC(H)RR′ = cyclo-NC4H8 (pyrrolidino), N(CH2Ph)2, OCH2Ph, OCH(Me)Ph, and CH2CH2Ph) takes place through formally analogous processes involving β-hydrogen elimination and reductive elimination of methane, cleanly affording corresponding Ni(0) imine, aldehyde, ketone, and olefin complexes, [Ni(η2-E═CRR′)(dippe)]. Kinetic studies on these decomposition reactions show that, in spite of their similarity, they involve substantial mechanistic differences.
Description9 páginas, 7 figuras, 6 esquemas.
Publisher version (URL)http://dx.doi.org/10.1021/om900400s
URIhttp://hdl.handle.net/10261/37705
DOI10.1021/om900400s
ISSN0276-7333
Appears in Collections:(IIQ) Artículos
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