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http://hdl.handle.net/10261/37700
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Campo DC | Valor | Lengua/Idioma |
---|---|---|
dc.contributor.author | Esqueda Oliva, Ana Cristina | - |
dc.contributor.author | Conejero, Salvador | - |
dc.contributor.author | Maya, Celia | - |
dc.contributor.author | Carmona, Ernesto | - |
dc.date.accessioned | 2011-07-12T12:57:10Z | - |
dc.date.available | 2011-07-12T12:57:10Z | - |
dc.date.issued | 2008-12-16 | - |
dc.identifier.citation | Organometallics 28(1): 45-47 (2009) | es_ES |
dc.identifier.issn | 0276-7333 | - |
dc.identifier.uri | http://hdl.handle.net/10261/37700 | - |
dc.description | 3 páginas, 1 figura, esquemas. | es_ES |
dc.description.abstract | The Rh(I) cyclopentadienyl olefin compounds [(η5-C5Me4R)Rh(olefin)2] (R = CMe3, SiMe3, SiMe2CMe3; olefin = C2H4, C2H3SiMe3) are readily prepared from the corresponding [RhCl(olefin)2]2 and zincocene, [Zn(C5Me4R)2], precursors. The new compounds undergo hydrogen/deuterium exchange at the olefinic sites in deuterated benzene, at a rate dependent on the cyclopentadienyl substituents. | es_ES |
dc.description.sponsorship | Financial support from the Spanish Ministerio de Educación y Ciencia (MEC) (Project No. CTQ2007-62814) and Consolider-Ingenio 2010 (No. CSD2007-00006) (FEDER support), the Junta de Andalucía (Project Nos. FQM-3151 and FQM-672) is gratefully acknowledged. A.C.E. thanks the CONACYT for a research grant (Ref. No. 229340). | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | American Chemical Society | es_ES |
dc.rights | closedAccess | es_ES |
dc.subject | Olefin | es_ES |
dc.subject | Zincocene | es_ES |
dc.subject | Benzene | es_ES |
dc.subject | Cyclopentadienyl complexes | es_ES |
dc.subject | Organometallic | es_ES |
dc.subject | Rhodium | es_ES |
dc.title | Zincocenes as Mild Cyclopentadienyl Transfer Reagents toward Rhodium(I) Olefin Precursors. Facile Synthesis of (η5-Cp′)Rh(olefin)2 Compounds | es_ES |
dc.type | artículo | es_ES |
dc.identifier.doi | 10.1021/om801046d | - |
dc.description.peerreviewed | Peer reviewed | es_ES |
dc.relation.publisherversion | http://dx.doi.org/10.1021/om801046d | es_ES |
dc.type.coar | http://purl.org/coar/resource_type/c_6501 | es_ES |
item.openairetype | artículo | - |
item.grantfulltext | none | - |
item.cerifentitytype | Publications | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.fulltext | No Fulltext | - |
item.languageiso639-1 | en | - |
Aparece en las colecciones: | (IIQ) Artículos |
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