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| Title: | Zincocenes as Mild Cyclopentadienyl Transfer Reagents toward Rhodium(I) Olefin Precursors. Facile Synthesis of (η5-Cp′)Rh(olefin)2 Compounds |
Authors: | Esqueda Oliva, Ana Cristina CSIC; Conejero, Salvador CSIC ORCID; Maya, Celia CSIC ORCID; Carmona, Ernesto CSIC ORCID | Keywords: | Olefin Zincocene Benzene Cyclopentadienyl complexes Organometallic Rhodium |
Issue Date: | 16-Dec-2008 | Publisher: | American Chemical Society | Citation: | Organometallics 28(1): 45-47 (2009) | Abstract: | The Rh(I) cyclopentadienyl olefin compounds [(η5-C5Me4R)Rh(olefin)2] (R = CMe3, SiMe3, SiMe2CMe3; olefin = C2H4, C2H3SiMe3) are readily prepared from the corresponding [RhCl(olefin)2]2 and zincocene, [Zn(C5Me4R)2], precursors. The new compounds undergo hydrogen/deuterium exchange at the olefinic sites in deuterated benzene, at a rate dependent on the cyclopentadienyl substituents. | Description: | 3 páginas, 1 figura, esquemas. | Publisher version (URL): | http://dx.doi.org/10.1021/om801046d | URI: | http://hdl.handle.net/10261/37700 | DOI: | 10.1021/om801046d | ISSN: | 0276-7333 |
| Appears in Collections: | (IIQ) Artículos |
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