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Please use this identifier to cite or link to this item: http://hdl.handle.net/10261/37700
Title: Zincocenes as Mild Cyclopentadienyl Transfer Reagents toward Rhodium(I) Olefin Precursors. Facile Synthesis of (η5-Cp′)Rh(olefin)2 Compounds
Authors: Esqueda Oliva, Ana Cristina; Conejero Iglesias, Salvador; Maya, Celia; Carmona Guzmán, Ernesto
Keywords: Olefin
Cyclopentadienyl complexes
Issue Date: 16-Dec-2008
Publisher: American Chemical Society
Citation: Organometallics 28(1): 45-47 (2009)
Abstract: The Rh(I) cyclopentadienyl olefin compounds [(η5-C5Me4R)Rh(olefin)2] (R = CMe3, SiMe3, SiMe2CMe3; olefin = C2H4, C2H3SiMe3) are readily prepared from the corresponding [RhCl(olefin)2]2 and zincocene, [Zn(C5Me4R)2], precursors. The new compounds undergo hydrogen/deuterium exchange at the olefinic sites in deuterated benzene, at a rate dependent on the cyclopentadienyl substituents.
Description: 3 páginas, 1 figura, esquemas.
Publisher version (URL): http://dx.doi.org/10.1021/om801046d
URI: http://hdl.handle.net/10261/37700
ISSN: 0276-7333
DOI: 10.1021/om801046d
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