DSpace

Digital.CSIC > Ciencia y Tecnologías Químicas > Instituto de Investigaciones Químicas (IIQ) > (IIQ) Artículos >

Share

EndNote

Impact

Links

Closed Access item Zincocenes as Mild Cyclopentadienyl Transfer Reagents toward Rhodium(I) Olefin Precursors. Facile Synthesis of (η5-Cp′)Rh(olefin)2 Compounds

Authors:Esqueda Oliva, Ana Cristina
Conejero Iglesias, Salvador
Maya, Celia
Carmona Guzmán, Ernesto
Keywords:Olefin, Zincocene, Benzene, Cyclopentadienyl complexes, Organometallic, Rhodium
Issue Date:16-Dec-2008
Publisher:American Chemical Society
Citation:Organometallics 28(1): 45-47 (2009)
Abstract:The Rh(I) cyclopentadienyl olefin compounds [(η5-C5Me4R)Rh(olefin)2] (R = CMe3, SiMe3, SiMe2CMe3; olefin = C2H4, C2H3SiMe3) are readily prepared from the corresponding [RhCl(olefin)2]2 and zincocene, [Zn(C5Me4R)2], precursors. The new compounds undergo hydrogen/deuterium exchange at the olefinic sites in deuterated benzene, at a rate dependent on the cyclopentadienyl substituents.
Description:3 páginas, 1 figura, esquemas.
Publisher version (URL):http://dx.doi.org/10.1021/om801046d
URI:http://hdl.handle.net/10261/37700
ISSN:0276-7333
???metadata.dc.identifier.doi???:10.1021/om801046d
Appears in Collections:(IIQ) Artículos

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.