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| Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL | DATACITE | |
| Campo DC | Valor | Lengua/Idioma |
|---|---|---|
| dc.contributor.author | Martín, Carmen | - |
| dc.contributor.author | Muñoz-Molina, José María | - |
| dc.contributor.author | Locati, Abel | - |
| dc.contributor.author | Álvarez, Eleuterio | - |
| dc.contributor.author | Maseras, Feliu | - |
| dc.contributor.author | Belderrain, Tomás R. | - |
| dc.contributor.author | Pérez, Pedro J. | - |
| dc.date.accessioned | 2011-07-11T11:51:29Z | - |
| dc.date.available | 2011-07-11T11:51:29Z | - |
| dc.date.issued | 2010-07-22 | - |
| dc.identifier.citation | Organometallics 29(16): 3481-3489 (2010) | es_ES |
| dc.identifier.issn | 0276-7333 | - |
| dc.identifier.uri | http://hdl.handle.net/10261/37660 | - |
| dc.description | 9 páginas, 4 figuras, 5 tablas, 4 esquemas. | es_ES |
| dc.description.abstract | The spectroscopic and structural characteristics and the relative reactivity of several TpMsCu(olefin) (olefin = ethylene, 1, 1-hexene, 2, allyl ethyl ether, aee, 3, cyclohexene, 4, and styrene, 5) complexes bearing the bulky hydrotris(3-mesitylpyrazolyl)borate ligand have been examined. Experimental data, including an unusual high-field chemical shift in the 1H and 13C NMR spectra, and DFT theoretical calculations support the proposal that the copper−olefin linkage is mainly sustained by σ-donation, lacking a substantial degree of π-back-donation. | es_ES |
| dc.description.sponsorship | We thank the MICINN (Proyecto CTQ2008−00042BQU, CTQ2008-06866-CO2-02/BQU and Consolider Ingenio 2010 grant CSD2006-0003), the Junta de Andalucía (Proyecto P07-FQM-02794), and the ICIQ Foundation for financial support. C.M. thanks the Ministerio de Educación for a research fellowship. | es_ES |
| dc.language.iso | eng | es_ES |
| dc.publisher | American Chemical Society | es_ES |
| dc.rights | closedAccess | es_ES |
| dc.subject | NMR spectra | es_ES |
| dc.subject | Olefin complexes | es_ES |
| dc.subject | Trispyrazolylborate | es_ES |
| dc.subject | Ethylene | es_ES |
| dc.title | Copper(I)−Olefin Complexes: The Effect of the Trispyrazolylborate Ancillary Ligand in Structure and Reactivity | es_ES |
| dc.type | artículo | es_ES |
| dc.identifier.doi | 10.1021/om1002705 | - |
| dc.description.peerreviewed | Peer reviewed | es_ES |
| dc.relation.publisherversion | http://dx.doi.org/10.1021/om1002705 | es_ES |
| dc.type.coar | http://purl.org/coar/resource_type/c_6501 | es_ES |
| item.openairetype | artículo | - |
| item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
| item.grantfulltext | none | - |
| item.fulltext | No Fulltext | - |
| item.languageiso639-1 | en | - |
| item.cerifentitytype | Publications | - |
| Aparece en las colecciones: | (IIQ) Artículos | |
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