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Título: | Intramolecular Benzyl Protection Delivery: A Practical Synthesis of DMDP and DGDP from d-Fructose |
Autor: | García Moreno, María Isabel; Aguilar Moncayo, Matilde; Ortiz-Mellet, Carmen; García Fernández, José Manuel CSIC ORCID | Palabras clave: | Ethers Fructose Imino pyranoses Mannitol Molecular structure Sorbitol Glycoside hydrolases Stereoisomerism |
Fecha de publicación: | 18-dic-2005 | Editor: | American Chemical Society | Citación: | Organic Letters 8(2): 297-299 (2006) | Resumen: | A two-step protection of 1,2-diols as the corresponding o-xylylene cyclic ethers, involving an intramolecular ring-closing O-benzylation reaction, has been developed to overcome the problems associated to regioselective benzylation reactions. The strategy has been applied to the high-yielding synthesis of the pyrrolidine glycosidase inhibitors DMDP and DGDP. | Descripción: | 3 páginas, 4 esquemas. | Versión del editor: | http://dx.doi.org/ 10.1021/ol052668u | URI: | http://hdl.handle.net/10261/37645 | DOI: | 10.1021/ol052668u | ISSN: | 1523-7060 |
Aparece en las colecciones: | (IIQ) Artículos |
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