Please use this identifier to cite or link to this item: http://hdl.handle.net/10261/37645
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Título : Intramolecular Benzyl Protection Delivery: A Practical Synthesis of DMDP and DGDP from d-Fructose
Autor : García Moreno, María Isabel, Aguilar Moncayo, Matilde, Ortiz-Mellet, Carmen, García-Fernández, José Manuel
Palabras clave : Ethers
Fructose
Imino pyranoses
Mannitol
Molecular structure
Sorbitol
Glycoside hydrolases
Stereoisomerism
Fecha de publicación : 18-Dec-2005
Editor: American Chemical Society
Citación : Organic Letters 8(2): 297-299 (2006)
Resumen: A two-step protection of 1,2-diols as the corresponding o-xylylene cyclic ethers, involving an intramolecular ring-closing O-benzylation reaction, has been developed to overcome the problems associated to regioselective benzylation reactions. The strategy has been applied to the high-yielding synthesis of the pyrrolidine glycosidase inhibitors DMDP and DGDP.
Descripción : 3 páginas, 4 esquemas.
Versión del editor: http://dx.doi.org/ 10.1021/ol052668u
URI : http://hdl.handle.net/10261/37645
ISSN: 1523-7060
DOI: 10.1021/ol052668u
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