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Closed Access item Imidazo[1,5-a]pyridine: A Versatile Architecture for Stable N-Heterocyclic Carbenes

Authors:Alcarazo, Manuel
Rosedable, Stephen J.
Cowley, Andrew R.
Fernández, Rosario
Brown, John M.
Lassaletta, José M.
Keywords:N-heterocyclic carbenes, Mesoionic carbenes, Imidazo[1,5-a]pyridinium
Issue Date:17-Feb-2005
Publisher:American Chemical Society
Citation:Journal of the American Chemical Society 127(10): 3290-3291 (2005)
Abstract:The imidazo[1,5-a]pyridine skeleton provides a versatile platform for the generation of new types of stable N-heterocyclic carbenes. Rh(I) mono- (6) and biscarbenes (7) from imidazo[1,5-a]pyridin-3-ylidenes (ImPy) and derivatives such as 13 from a mesoionic carbene were synthesized and characterized.
Description:2 páginas, 1 figura, 2 tablas, esquemas.
Publisher version (URL):http://dx.doi.org/10.1021/ja0423769
URI:http://hdl.handle.net/10261/37479
ISSN:0002-7863
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Appears in Collections:(IIQ) Artículos

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