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A convenient synthesis of bis(phosphino)methanes: Formation of a nickel(II) bis(phosphino)methane monoxide complex

AuthorsCámpora, Juan ; Maya, Celia ; Matas, Inmaculada ; Claasen, Birgit; Palma, Pilar ; Álvarez, Eleuterio
KeywordsDiphosphine ligands
Diphosphine monoxide
Issue Date5-Apr-2006
CitationInorganica Chimica Acta 359(10): 3191-3196 (2006)
AbstractThe reaction of (trimethylsilyl)methyl phosphines R2PCH2SiMe3 with chlorophosphines CLPR'2 provides ready access to a range of symmetrical or non-symmetrical diphosphinomethanes R2PCH2PR'2 . The products are obtained cleanly and can be used directly in the synthesis of transition metal complexes. This is illustrated by the preparation and structural characterization of the corresponding NiCl2(P–P) derivatives.
Description6 páginas, 2 figuras, 2 tablas, 2 esquemas.
Publisher version (URL)http://dx.doi.org/10.1016/j.ica.2005.12.053
Appears in Collections:(IIQ) Artículos
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