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Título : A convenient synthesis of bis(phosphino)methanes: Formation of a nickel(II) bis(phosphino)methane monoxide complex
Autor : Cámpora, Juan, Maya, Celia, Matas, Inmaculada, Claasen, Birgit, Palma Ramírez, Pilar, Álvarez, Eleuterio
Palabras clave : Diphosphine ligands
Diphosphine monoxide
Fecha de publicación : 5-Apr-2006
Editor: Elsevier
Resumen: The reaction of (trimethylsilyl)methyl phosphines R2PCH2SiMe3 with chlorophosphines CLPR'2 provides ready access to a range of symmetrical or non-symmetrical diphosphinomethanes R2PCH2PR'2 . The products are obtained cleanly and can be used directly in the synthesis of transition metal complexes. This is illustrated by the preparation and structural characterization of the corresponding NiCl2(P–P) derivatives.
Descripción : 6 páginas, 2 figuras, 2 tablas, 2 esquemas.
Versión del editor:
ISSN: 0020-1693
DOI: 10.1016/j.ica.2005.12.053
Citación : Inorganica Chimica Acta 359(10): 3191-3196 (2006)
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