Por favor, use este identificador para citar o enlazar a este item:
http://hdl.handle.net/10261/37394
COMPARTIR / EXPORTAR:
SHARE CORE BASE | |
Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL | DATACITE | |
Campo DC | Valor | Lengua/Idioma |
---|---|---|
dc.contributor.author | Grirrane, Abdessamad | - |
dc.contributor.author | Pastor, Antonio | - |
dc.contributor.author | Álvarez, Eleuterio | - |
dc.contributor.author | Mealli, Carlo | - |
dc.contributor.author | Ienco, Andrea | - |
dc.contributor.author | Masi, Dante | - |
dc.contributor.author | Galindo, Agustín | - |
dc.date.accessioned | 2011-06-30T12:25:16Z | - |
dc.date.available | 2011-06-30T12:25:16Z | - |
dc.date.issued | 2005-03-23 | - |
dc.identifier.citation | Inorganic Chemistry Communications 8(5): 463-466 (2005) | es_ES |
dc.identifier.issn | 1387-7003 | - |
dc.identifier.uri | http://hdl.handle.net/10261/37394 | - |
dc.description | 4 páginas, 2 figuras, 1 tabla, esquemas | es_ES |
dc.description.abstract | The novel cobalt thiodiacetate complex [Co(tda)(H2O)]n (1a)(tda=S(CH2COO)2-) was synthesized from the reaction of aqueous solutions of cobalt dichloride with a 1:1 mixture of Na2CO3 and thiodiacetic acid. A second isomer was also obtained occasionally and identified as complex [Co(tda)(H2O)3] (1b). The reaction of 1a with 2,2′-bipyridine (bipy) gave compound [Co(tda)(bipy)(H2O)] · 4H2O (2), which has been structurally characterized and represents, to our knowledge, the first X-ray determination of a thiodiacetate–cobalt complex. The coordination is monomeric pseudo-octahedral as determined by the typical tridentate thiodiacetate ligand with a facial configuration, the chelate bipy ligand and one water molecule. Conversely, the interaction of bis(2-pyridyl)ketone with 1a afforded the compound [Co{OC(OH)(2-pyridyl)2}2]+[Htda]− · 3H2O (3), as confirmed from an X-ray analysis. The bis(2-pyridyl)ketone ligand is hydrolyzed with a concomitant oxidation of the metal to Co(III), a process which has been previously described, while the tda ligand, displaced from the coordination sphere, is monoprotonated and acts as counterion. | es_ES |
dc.description.sponsorship | Thanks are expressed to the Ministerio de Educación y Ciencia (BQU2001-3715 and CTQ2004-84) and Junta de Andalucía for financial support. | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | Elsevier | es_ES |
dc.rights | closedAccess | es_ES |
dc.subject | Cobalt (II) | es_ES |
dc.subject | Thiodiacetate | es_ES |
dc.subject | thiodiglycolate | es_ES |
dc.subject | Crystal structures | es_ES |
dc.title | Thiodiacetate cobalt(II) complexes: Synthesis, structure and properties | es_ES |
dc.type | artículo | es_ES |
dc.identifier.doi | 10.1016/j.inoche.2005.02.011 | - |
dc.description.peerreviewed | Peer reviewed | es_ES |
dc.relation.publisherversion | http://dx.doi.org/10.1016/j.inoche.2005.02.011 | es_ES |
dc.type.coar | http://purl.org/coar/resource_type/c_6501 | es_ES |
item.languageiso639-1 | en | - |
item.fulltext | No Fulltext | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.cerifentitytype | Publications | - |
item.grantfulltext | none | - |
item.openairetype | artículo | - |
Aparece en las colecciones: | (IIQ) Artículos |
CORE Recommender
SCOPUSTM
Citations
32
checked on 20-abr-2024
WEB OF SCIENCETM
Citations
32
checked on 24-feb-2024
Page view(s)
342
checked on 24-abr-2024
Google ScholarTM
Check
Altmetric
Altmetric
NOTA: Los ítems de Digital.CSIC están protegidos por copyright, con todos los derechos reservados, a menos que se indique lo contrario.