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Closed Access item Coupling Radical and Ionic Processes: An Unusual Rearrangement Affords Sugar and C-Glycoside Derivatives

Authors:Boto, Alicia
Hernández, Dácil
Hernández, Rosendo
Álvarez, Eleuterio
Keywords:Radical reactions, Rearrangement, Carbohydrates, Sequential processes, Photochemistry
Issue Date:29-Jun-2009
Publisher:Wiley-VCH
Citation:European Journal of Organic Chemistry (23): 3853-3857 (2009)
Abstract:An unusual scission–rearrangement process, which couples radical and ionic reactions, was observed with galactofuranose derivatives. This one-pot procedure afforded, in good yields, highly functionalized 1,4-dioxanes, which could be considered as six-membered-ring sugar analogues. The synthesis of C-glycoside analogues is also possible with this methodology.
Description:5 páginas, 2 figuras, 2 tablas, 6 esquemas.
Publisher version (URL):http://dx.doi.org/10.1002/ejoc.200900427
URI:http://hdl.handle.net/10261/37217
ISSN:1434-193X
E-ISSNmetadata.dc.identifier.doi = DOI:1099-0690
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