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Please use this identifier to cite or link to this item: http://hdl.handle.net/10261/37217
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Title: Coupling Radical and Ionic Processes: An Unusual Rearrangement Affords Sugar and C-Glycoside Derivatives
Authors: Boto, Alicia ; Hernández, Dácil ; Hernández, Rosendo ; Álvarez, Eleuterio
Keywords: Radical reactions
Rearrangement
Carbohydrates
Sequential processes
Photochemistry
Issue Date: 29-Jun-2009
Publisher: Wiley-VCH
Citation: European Journal of Organic Chemistry (23): 3853-3857 (2009)
Abstract: An unusual scission–rearrangement process, which couples radical and ionic reactions, was observed with galactofuranose derivatives. This one-pot procedure afforded, in good yields, highly functionalized 1,4-dioxanes, which could be considered as six-membered-ring sugar analogues. The synthesis of C-glycoside analogues is also possible with this methodology.
Description: 5 páginas, 2 figuras, 2 tablas, 6 esquemas.
Publisher version (URL): http://dx.doi.org/10.1002/ejoc.200900427
URI: http://hdl.handle.net/10261/37217
ISSN: 1434-193X
DOI: 10.1002/ejoc.200900427
E-ISSN: 1099-0690
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