Please use this identifier to cite or link to this item: http://hdl.handle.net/10261/36996
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Título : Highly Enantioselective Hydrogenation of Enol Ester Phosphonates: A Versatile Procedure for the Preparation of Chiral β-Hydroxyphosphonates
Autor : Vargas Rodríguez, Sergio, Suárez Escobar, Andrés Luis, Álvarez, Eleuterio, Pizzano Mancera, Antonio
Palabras clave : Asymmetric catalysis
Hydrogention
P ligands
Rhodium
Fecha de publicación : 24-Sep-2008
Editor: Wiley-VCH
Citación : Chemistry - a European Journal 14(32): 9856-9859 (2008)
Resumen: P–OP ′til you drop: Rhodium catalysts with chiral phosphane–phosphite ligands (P–OP) facilitate the enantioselective hydrogenation of β-acyloxy α,β-unsaturated phosphonates, affording β-acyloxyphosphonates in high enantiomeric excess (see scheme). These products can be easily converted into synthetically valuable β-hydroxyphosphonates without racemization.
Descripción : 4 páginas, 2 tablas, 6 esquemas. Corrected by: Corrigendum: Highly Enantioselective Hydrogenation of Enol Ester Phosphonates: A Versatile Procedure for the Preparation of Chiral β-Hydroxyphosphonates Vol. 16, Issue 33, 9937.
Versión del editor: http://dx.doi.org/10.1002/chem.200801588
URI : http://hdl.handle.net/10261/36996
ISSN: 0947-6539
DOI: 10.1002/chem.200801588
Citación : Chemistry - a European Journal 14(32): 9856-9859 (2008)
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