DSpace

Digital.CSIC > Ciencia y Tecnologías Químicas > Instituto de Investigaciones Químicas (IIQ) > (IIQ) Artículos >

Share

EndNote

Impact

Links

Closed Access item Highly Enantioselective Hydrogenation of Enol Ester Phosphonates: A Versatile Procedure for the Preparation of Chiral β-Hydroxyphosphonates

Authors:Vargas Rodríguez, Sergio
Suárez Escobar, Andrés Luis
Álvarez, Eleuterio
Pizzano Mancera, Antonio
Keywords:Asymmetric catalysis, Hydrogention, P ligands, Rhodium
Issue Date:24-Sep-2008
Publisher:Wiley-VCH
Citation:Chemistry - a European Journal 14(32): 9856-9859 (2008)
Abstract:P–OP ′til you drop: Rhodium catalysts with chiral phosphane–phosphite ligands (P–OP) facilitate the enantioselective hydrogenation of β-acyloxy α,β-unsaturated phosphonates, affording β-acyloxyphosphonates in high enantiomeric excess (see scheme). These products can be easily converted into synthetically valuable β-hydroxyphosphonates without racemization.
Description:4 páginas, 2 tablas, 6 esquemas. Corrected by: Corrigendum: Highly Enantioselective Hydrogenation of Enol Ester Phosphonates: A Versatile Procedure for the Preparation of Chiral β-Hydroxyphosphonates Vol. 16, Issue 33, 9937.
Publisher version (URL):http://dx.doi.org/10.1002/chem.200801588
URI:http://hdl.handle.net/10261/36996
ISSN:0947-6539
E-ISSNmetadata.dc.identifier.doi = DOI:1521-3765
???metadata.dc.identifier.doi???:10.1002/chem.200801588
Appears in Collections:(IIQ) Artículos

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.