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Título: | Organocatalytic Asymmetric Cyanosilylation of Nitroalkenes |
Autor: | Bernal, Pablo; Fernández, Rosario; Lassaletta, José M. CSIC ORCID | Palabras clave: | Asymmetric catalysis Bifunctional catalysis Conjugate additions Nitroalkenes Organocatalysis Synthetic methods |
Fecha de publicación: | 8-jun-2010 | Editor: | Wiley-VCH | Citación: | Chemistry - A European Journal 16(26): 7714-7718 (2010) | Resumen: | New catalyst, new reaction: The unprecedented cyanosilylation of nitroalkenes can be efficiently catalyzed by a bifunctional quinine derivative with tetraalkylammonium cyanide and thiourea moieties. The activation of the nitroalkene by hydrogen bonding to the thiourea, together with the presence of an “active” cyanide, provides a new mode of activation that leads to products in high yields and good selectivities (see scheme). | Descripción: | 5 páginas, 1 figura, 5 esquemas | Versión del editor: | http://dx.doi.org/10.1002/chem.201001107 | URI: | http://hdl.handle.net/10261/36513 | DOI: | 10.1002/chem.201001107 | ISSN: | 0947-6539 | E-ISSN: | 1521-3765 |
Aparece en las colecciones: | (IIQ) Artículos |
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