Please use this identifier to cite or link to this item: http://hdl.handle.net/10261/36379
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Título : Cyclometallation and Hydrogen/Deuterium Exchange Reactions of an Arylphosphine Ligand upon Coordination to {IrACHTUNGTRENUNG(h5-C5Me5)}
Autor : Campos, Jesús, Esqueda Oliva, Ana Cristina, Carmona Guzmán, Ernesto
Palabras clave : C-H activation
Irridium
Metallacycles
Phosphanes
Fecha de publicación : 11-Jan-2010
Editor: Wiley-VCH
Resumen: Which way to go? The cyclometallated compounds [(η5-C5Me5)Ir(X){PMe(2,6-CH2(Me)C6H3)(2,6-Me2C6H3)}] (X=Cl, H, Me) have been synthesized in high yields and their potential for C-H activation demonstrated. Deuterium incorporation into the metallated ligand backbone has been achieved for X=Cl and X=H, with dissimilar results and hence through different reaction pathways.
Descripción : 4 páginas, 4 esquemas
Versión del editor: http://dx.doi.org/10.1002/chem.200902791
URI : http://hdl.handle.net/10261/36379
ISSN: 1521-3765
DOI: 10.1002/chem.200902791
Citación : Chemistry - A European Journal 16(2): 419-422 (2010)
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