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Closed Access item Cyclometallation and Hydrogen/Deuterium Exchange Reactions of an Arylphosphine Ligand upon Coordination to {IrACHTUNGTRENUNG(h5-C5Me5)}

Authors:Campos, Jesús
Esqueda Oliva, Ana Cristina
Carmona Guzmán, Ernesto
Keywords:C-H activation, Irridium, Metallacycles, Phosphanes
Issue Date:11-Jan-2010
Publisher:Wiley-VCH
Citation:Chemistry - A European Journal 16(2): 419-422 (2010)
Abstract:Which way to go? The cyclometallated compounds [(η5-C5Me5)Ir(X){PMe(2,6-CH2(Me)C6H3)(2,6-Me2C6H3)}] (X=Cl, H, Me) have been synthesized in high yields and their potential for C-H activation demonstrated. Deuterium incorporation into the metallated ligand backbone has been achieved for X=Cl and X=H, with dissimilar results and hence through different reaction pathways.
Description:4 páginas, 4 esquemas
Publisher version (URL):http://dx.doi.org/10.1002/chem.200902791
URI:http://hdl.handle.net/10261/36379
ISSN:1521-3765
E-ISSNmetadata.dc.identifier.doi = DOI:0947-6539
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Appears in Collections:(IIQ) Artículos

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