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Please use this identifier to cite or link to this item: http://hdl.handle.net/10261/36379
Title: Cyclometallation and Hydrogen/Deuterium Exchange Reactions of an Arylphosphine Ligand upon Coordination to {IrACHTUNGTRENUNG(h5-C5Me5)}
Authors: Campos, Jesús; Esqueda Oliva, Ana Cristina; Carmona, Ernesto
Keywords: C-H activation
Issue Date: 11-Jan-2010
Publisher: Wiley-VCH
Citation: Chemistry - A European Journal 16(2): 419-422 (2010)
Abstract: Which way to go? The cyclometallated compounds [(η5-C5Me5)Ir(X){PMe(2,6-CH2(Me)C6H3)(2,6-Me2C6H3)}] (X=Cl, H, Me) have been synthesized in high yields and their potential for C-H activation demonstrated. Deuterium incorporation into the metallated ligand backbone has been achieved for X=Cl and X=H, with dissimilar results and hence through different reaction pathways.
Description: 4 páginas, 4 esquemas
Publisher version (URL): http://dx.doi.org/10.1002/chem.200902791
URI: http://hdl.handle.net/10261/36379
DOI: 10.1002/chem.200902791
ISSN: 1521-3765
E-ISSN: 0947-6539
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