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Título : T-Shaped Platinum(II) Complexes Stabilised by Bulky N-Heterocyclic Carbene Ligands
Autor : Rivada-Wheelaghan, Orestes, Donnadieu, Bruno, Maya, Celia, Conejero Iglesias, Salvador
Palabras clave : Agostic interactions
C-H activation
Nitrogen heterocycles
T-shaped complexes
Fecha de publicación : 23-Jul-2010
Editor: Wiley-VCH
Citación : Chemistry - A European Journal 16(24): 10323-10326 (2010)
Resumen: Pt to a T! Treating bulky N-heterocyclic carbene (NHC) ligands with [PtMe3I]4 results in rapid elimination of ethene and formation of [PtMeI(NHC)2] complexes. These complexes are suitable materials for the synthesis of T-shaped platinum(II) complexes stabilised by agostic interactions. X-ray structure determination of one of these complexes shows a rather long ζ agostic interaction.
Descripción : 5 páginas, 3 figuras, 5 esquemas.
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ISSN: 1521-3765
DOI: 10.1002/chem.201000955
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