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Open Access item T-Shaped Platinum(II) Complexes Stabilised by Bulky N-Heterocyclic Carbene Ligands

Authors:Rivada-Wheelaghan, Orestes
Donnadieu, Bruno
Maya, Celia
Conejero Iglesias, Salvador
Keywords:Agostic interactions, C-H activation, Nitrogen heterocycles, Platinum, T-shaped complexes
Issue Date:23-Jul-2010
Publisher:Wiley-VCH
Citation:Chemistry - A European Journal 16(24): 10323-10326 (2010)
Abstract:Pt to a T! Treating bulky N-heterocyclic carbene (NHC) ligands with [PtMe3I]4 results in rapid elimination of ethene and formation of [PtMeI(NHC)2] complexes. These complexes are suitable materials for the synthesis of T-shaped platinum(II) complexes stabilised by agostic interactions. X-ray structure determination of one of these complexes shows a rather long ζ agostic interaction.
Description:5 páginas, 3 figuras, 5 esquemas.
Publisher version (URL):http://dx.doi.org/10.1002/chem.201000955
URI:http://hdl.handle.net/10261/36376
ISSN:1521-3765
E-ISSNmetadata.dc.identifier.doi = DOI:0947-6539
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Appears in Collections:(IIQ) Artículos

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