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Please use this identifier to cite or link to this item: http://hdl.handle.net/10261/36376
Title: T-Shaped Platinum(II) Complexes Stabilised by Bulky N-Heterocyclic Carbene Ligands
Authors: Rivada-Wheelaghan, Orestes; Donnadieu, Bruno; Maya, Celia; Conejero Iglesias, Salvador
Keywords: Agostic interactions
C-H activation
Nitrogen heterocycles
T-shaped complexes
Issue Date: 23-Jul-2010
Publisher: Wiley-VCH
Citation: Chemistry - A European Journal 16(24): 10323-10326 (2010)
Abstract: Pt to a T! Treating bulky N-heterocyclic carbene (NHC) ligands with [PtMe3I]4 results in rapid elimination of ethene and formation of [PtMeI(NHC)2] complexes. These complexes are suitable materials for the synthesis of T-shaped platinum(II) complexes stabilised by agostic interactions. X-ray structure determination of one of these complexes shows a rather long ζ agostic interaction.
Description: 5 páginas, 3 figuras, 5 esquemas.
Publisher version (URL): http://dx.doi.org/10.1002/chem.201000955
URI: http://hdl.handle.net/10261/36376
ISSN: 1521-3765
DOI: 10.1002/chem.201000955
E-ISSN: 0947-6539
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