Please use this identifier to cite or link to this item: http://hdl.handle.net/10261/36340
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Título : Isoquinolin-1-ylidenes as electronically tuneable ligands
Autor : Gómez-Bujedo, Silvia, Alcarazo, Manuel, Pichon, Christophe, Álvarez, Eleuterio, Lassaletta, José M.
Palabras clave : Isoquinolin-1-ylidene
Rh(I)
Carbene
NHC
Benzene
Fecha de publicación : 10-Jan-2006
Editor: Royal Society of Chemistry (Great Britain)
Citación : Chemical Communications (11): 1180-1182 (2007)
Resumen: The novel isoquinolin-1-ylidene ligands, introduced into Rh(I) complexes by exploiting the carbene-like reactivity of adducts 6, exhibit ligand properties similar to those of classic NHCs, and their electronic properties can be tuned by the introduction of electron-withdrawing or donating groups in the benzene ring.
Descripción : 3 páginas, 1 figura, 1 tabla, 4 esquemas.
Versión del editor: http://dx.doi.org/10.1039/B617037D
URI : http://hdl.handle.net/10261/36340
ISSN: 1359-7345
DOI: 10.1039/B617037D
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