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Closed Access item Isoquinolin-1-ylidenes as electronically tuneable ligands

Authors:Gómez-Bujedo, Silvia
Alcarazo, Manuel
Pichon, Christophe
Álvarez, Eleuterio
Lassaletta, José M.
Keywords:Isoquinolin-1-ylidene, Rh(I), Carbene, NHC, Benzene
Issue Date:10-Jan-2006
Publisher:Royal Society of Chemistry
Citation:Chemical Communications (11): 1180-1182 (2007)
Abstract:The novel isoquinolin-1-ylidene ligands, introduced into Rh(I) complexes by exploiting the carbene-like reactivity of adducts 6, exhibit ligand properties similar to those of classic NHCs, and their electronic properties can be tuned by the introduction of electron-withdrawing or donating groups in the benzene ring.
Description:3 páginas, 1 figura, 1 tabla, 4 esquemas.
Publisher version (URL):http://dx.doi.org/10.1039/B617037D
URI:http://hdl.handle.net/10261/36340
ISSN:1359-7345
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Appears in Collections:(IIQ) Artículos

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