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Title

One-pot regioselective synthesis of 2I,3I-O-(o-xylylene)-capped cyclomaltooligosaccharides: tailoring the topology and supramolecular properties of cyclodextrins

AuthorsBalbuena Olivia, Patricia ; Lesur, David; González-Álvarez, M. José; Mendicuti, Francisco; Ortiz-Mellet, Carmen; García-Fernández, José Manuel
Keywordsα′-dibromo-o-xylylene
Hydroxyls
Glucopyranosyl
Cyclodextrins
Cyclomaltooligosaccharides
Issue Date8-Jun-2007
PublisherRoyal Society of Chemistry
CitationChemical Communications (31): 3270-3272 (2007)
AbstractThe α,α′-dibromo-o-xylylene cap has been installed at the secondary hydroxyls of a single glucopyranosyl residue in cyclodextrins in one pot and with total regioselectivity; the resulting cyclic ether acts as a removable hinge, allowing selective elaboration of the secondary face and modulating both the self-association and the inclusion capabilities of the hosts.
Description3 páginas, 3 figuras, 2 esquemas.
Publisher version (URL)http://dx.doi.org/10.1039/B705644C
URIhttp://hdl.handle.net/10261/36338
DOI10.1039/B705644C
ISSN1359-7345
Appears in Collections:(IIQ) Artículos
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