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Please use this identifier to cite or link to this item: http://hdl.handle.net/10261/36325
Title: Synthesis and structural characterization of a binuclear iridium complex with bridging, bidentate N-heterocyclic carbene coordination of 2,2′:6′,2″-terpyridine
Authors: Paneque, Margarita; López Poveda, Manuel; Vattier, Florencia; Álvarez, Eleuterio; Carmona, Ernesto
Keywords: Terpyridine
Hydrotris (pirazolilo) borato
Mononuclear complex
N-heterocyclic carbene
Issue Date: 18-Aug-2009
Publisher: Royal Society of Chemistry (Great Britain)
Citation: Chemical Communications (37): 5561-5563 (2009)
Abstract: Thermal activation of terpyridine in the presence of an unsaturated Ir(III) fragment stabilized by a hydrotris(pyrazolyl) borate ligand gives rise to mononuclear complex 2 and binuclear 3, in which the polypyridine behaves, respectively, as a mono- or a bi-dentate N-heterocyclic carbene.
Description: 3 páginas, 2 figuras, 2 esquemas.
Publisher version (URL): http://dx.doi.org/10.1039/B909837B
URI: http://hdl.handle.net/10261/36325
DOI: 10.1039/B909837B
ISSN: 1359-7345
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