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Closed Access item Synthesis and structural characterization of a binuclear iridium complex with bridging, bidentate N-heterocyclic carbene coordination of 2,2′:6′,2″-terpyridine

Authors:Paneque, Margarita
López Poveda, Manuel
Vattier, Florencia
Álvarez, Eleuterio
Carmona Guzmán, Ernesto
Keywords:Terpyridine, Ir(III), Hydrotris (pirazolilo) borato, Mononuclear complex, Polypyridine, N-heterocyclic carbene
Issue Date:18-Aug-2009
Publisher:Royal Society of Chemistry (Great Britain)
Citation:Chemical Communications (37): 5561-5563 (2009)
Abstract:Thermal activation of terpyridine in the presence of an unsaturated Ir(III) fragment stabilized by a hydrotris(pyrazolyl) borate ligand gives rise to mononuclear complex 2 and binuclear 3, in which the polypyridine behaves, respectively, as a mono- or a bi-dentate N-heterocyclic carbene.
Description:3 páginas, 2 figuras, 2 esquemas.
Publisher version (URL):http://dx.doi.org/10.1039/B909837B
URI:http://hdl.handle.net/10261/36325
ISSN:1359-7345
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Appears in Collections:(IIQ) Artículos

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