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Title: H-1 NMR study of the conformation of metallapentacycles N-C-C-O-M [M=Rh(III) and Ir(III)] resulting in a Karplus-type relationship for vicinal H-C(sp(3))-N(sp(3))-H coupling constants
Authors: Jimeno, M. Luisa, Elguero, José, Carmona, Daniel, Lamata, M. Pilar, San Jose, Emilio
Keywords: NMR
'H,'H vicinal coupling constants
Karplus-type relationship
conformational analysis
five-membered metallacycles
aminoacidate complexes
Issue Date: 1996
Publisher: John Wiley & Sons
Abstract: The complete analysis of the 'H NMR spectra of [ (C,Me,)lr(glycinate)CI] and [ (C,Me,)Ir(N-methylg1ycinate) Clj provide information for the conformational analysis of the five-membered N-C-C-0-Ir ring. A Karplus relationship has been established for these metallacycles [ 3J(H,H) = 8.9 cos' 4 - 1.0 cos 4 + 0.81
Publisher version (URL):<42::AID-OMR827>3.0.CO;2-9
ISSN: 0749-1581
???metadata.dc.identifier.doi???: 10.1002/(SICI)1097-458X(199601)34:1<42::AID-OMR827>3.0.CO;2-9
Citation: Magnetic Resonance in Chemistry 34 : 42-46 (1996)
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