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| Title: | Selective reduction of a Pd pincer PCP complex to well-defined Pd(0) species |
Authors: | Melero, Cristobal CSIC; Martínez-Prieto, Luis Miguel CSIC ORCID; Palma, Pilar CSIC ORCID; Río, Diego del; Álvarez, Eleuterio CSIC ORCID ; Cámpora, Juan CSIC ORCID | Keywords: | Pd PCP Pd(0) Dimeric Polymeric Cyclometallated Methanol Isopropanol |
Issue Date: | 21-Oct-2010 | Publisher: | Royal Society of Chemistry (UK) | Citation: | Chemical Communications 46(46): 8851-8853 (2010) | Abstract: | Well-defined dimeric or polymeric Pd(0) complexes [Pd(μ-iPrPCHP)]n (n = 2 or ∞) containing the bridging ligand α,α′-bis(diisopropylphosphino)-m-xylene (iPrPCHP) are produced under mild conditions when the cyclometallated PCP pincer complex (iPrPCP)Pd–OH reacts with methanol or isopropanol. | Description: | 3 páginas, 1 figura, 3 esquemas. | Publisher version (URL): | http://dx.doi.org/10.1039/C0CC02972F | URI: | http://hdl.handle.net/10261/36294 | DOI: | 10.1039/C0CC02972F | ISSN: | 1359-7345 |
| Appears in Collections: | (IIQ) Artículos |
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