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Please use this identifier to cite or link to this item: http://hdl.handle.net/10261/36294
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Title: Selective reduction of a Pd pincer PCP complex to well-defined Pd(0) species
Authors: Melero, Cristóbal; Martínez-Prieto, Luis Miguel; Palma, Pilar; Río, Diego del; Álvarez, Eleuterio; Cámpora, Juan
Keywords: Pd
PCP
Pd(0)
Dimeric
Polymeric
Cyclometallated
Methanol
Isopropanol
Issue Date: 21-Oct-2010
Publisher: Royal Society of Chemistry (Great Britain)
Citation: Chemical Communications 46(46): 8851-8853 (2010)
Abstract: Well-defined dimeric or polymeric Pd(0) complexes [Pd(μ-iPrPCHP)]n (n = 2 or ∞) containing the bridging ligand α,α′-bis(diisopropylphosphino)-m-xylene (iPrPCHP) are produced under mild conditions when the cyclometallated PCP pincer complex (iPrPCP)Pd–OH reacts with methanol or isopropanol.
Description: 3 páginas, 1 figura, 3 esquemas.
Publisher version (URL): http://dx.doi.org/10.1039/C0CC02972F
URI: http://hdl.handle.net/10261/36294
DOI: 10.1039/C0CC02972F
ISSN: 1359-7345
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