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Closed Access item Selective reduction of a Pd pincer PCP complex to well-defined Pd(0) species

Authors:Melero, Cristóbal
Martínez-Prieto, Luis Miguel
Palma Ramírez, Pilar
Río, Diego del
Álvarez, Eleuterio
Cámpora, Juan
Keywords:Pd, PCP, Pd(0), Dimeric, Polymeric, Cyclometallated, Methanol, Isopropanol
Issue Date:21-Oct-2010
Publisher:Royal Society of Chemistry (Great Britain)
Citation:Chemical Communications 46(46): 8851-8853 (2010)
Abstract:Well-defined dimeric or polymeric Pd(0) complexes [Pd(μ-iPrPCHP)]n (n = 2 or ∞) containing the bridging ligand α,α′-bis(diisopropylphosphino)-m-xylene (iPrPCHP) are produced under mild conditions when the cyclometallated PCP pincer complex (iPrPCP)Pd–OH reacts with methanol or isopropanol.
Description:3 páginas, 1 figura, 3 esquemas.
Publisher version (URL):http://dx.doi.org/10.1039/C0CC02972F
URI:http://hdl.handle.net/10261/36294
ISSN:1359-7345
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Appears in Collections:(IIQ) Artículos

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