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Closed Access item Monodentate, N-Heterocyclic Carbene-Type Coordination of 2,2′-Bipyridine and 1,10-Phenanthroline to Iridium

Authors:Conejero Iglesias, Salvador
Lara, Patricia
Guerreiro de Brito Petronilho, Ana Rita
López Poveda, Manuel
Serrano, Oracio
Vattier, Florencia
Álvarez, Eleuterio
Maya, Celia
Salazar, Verónica
Carmona Guzmán, Ernesto
Keywords:Iridium, N ligands, N-heterocyclic carbenes, Nitrogen heterocycles, Polypyridines
Issue Date:30-Apr-2008
Publisher:Wiley-VCH
Citation:Angewandte Chemie - International Edition 47(23): 4380-4383 (2008)
Abstract:2,2′-Bipyridine and 1,10-phenanthroline are capable of coordinating to iridium as monodentate N-heterocyclic carbene ligands stabilized by NH⋅⋅⋅N bonding. This reactivity leads to complexes like 1 and their analogues with 2 as the carbene ligand. [Ir]: [hydrotris(3,5-dimethylpyrazolyl)borate]iridium.
Description:4 páginas, figuras
Publisher version (URL):http://dx.doi.org/10.1002/anie.200800705
URI:http://hdl.handle.net/10261/36092
ISSN:1433-7851
E-ISSNmetadata.dc.identifier.doi = DOI:1521-3773
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Appears in Collections:(IIQ) Artículos

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