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Título : Monodentate, N-Heterocyclic Carbene-Type Coordination of 2,2′-Bipyridine and 1,10-Phenanthroline to Iridium
Autor : Conejero Iglesias, Salvador, Lara, Patricia, Guerreiro de Brito Petronilho, Ana Rita, López Poveda, Manuel, Serrano, Oracio, Vattier, Florencia, Álvarez, Eleuterio, Maya, Celia, Salazar, Verónica, Carmona Guzmán, Ernesto
Palabras clave : Iridium
N ligands
N-heterocyclic carbenes
Nitrogen heterocycles
Fecha de publicación : 30-Apr-2008
Editor: Wiley-VCH
Citación : Angewandte Chemie - International Edition 47(23): 4380-4383 (2008)
Resumen: 2,2′-Bipyridine and 1,10-phenanthroline are capable of coordinating to iridium as monodentate N-heterocyclic carbene ligands stabilized by NH⋅⋅⋅N bonding. This reactivity leads to complexes like 1 and their analogues with 2 as the carbene ligand. [Ir]: [hydrotris(3,5-dimethylpyrazolyl)borate]iridium.
Descripción : 4 páginas, figuras
Versión del editor:
ISSN: 1433-7851
DOI: 10.1002/anie.200800705
Citación : Angewandte Chemie - International Edition 47(23): 4380-4383 (2008)
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