English   español  
Please use this identifier to cite or link to this item: http://hdl.handle.net/10261/36076
Share/Impact:
Statistics
logo share SHARE logo core CORE   Add this article to your Mendeley library MendeleyBASE

Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL
Exportar a otros formatos:
Title

Integrating catalyst and co-catalyst design in olefin polymerization catalysis: Transferable dianionic ligands for the activation of late transition metal polymerization catalysts

AuthorsBrasse, Mikaël ; Cámpora, Juan ; Davies, Maxwell; Teuma, Emmanuelle; Palma, Pilar ; Álvarez, Eleuterio ; Sanz, E.; Reyes, Manuel L.
KeywordsAluminum
Catalyst design
Nickel
Palladium
Polymerization
Issue Date11-Sep-2007
PublisherWiley-VCH
CitationAdvanced Synthesis and Catalysis 349: 2111-2120 (2007)
AbstractTreatment of nickel and palladium alpha-diimine catecholate complexes with alkylaluminum catecholates leads to active ethylene polymerization catalysts. Comparison of the catalytic activities achieved with combinations of alpha-diimine catecholate or halide complexes as catalyst precursors with different activators (MMAO or alkylaluminum catecholates) reveals that the presence of the catecholate ligand in both catalyst components is beneficial for achieving high activity levels at very low M/Al ratios.
Description10 páginas, figuras
Publisher version (URL)http://dx.doi.org/10.1002/adsc.200700196
URIhttp://hdl.handle.net/10261/36076
DOI10.1002/adsc.200700196
ISSN1615-4150
Appears in Collections:(IIQ) Artículos
Files in This Item:
There are no files associated with this item.
Show full item record
 

Related articles:


WARNING: Items in Digital.CSIC are protected by copyright, with all rights reserved, unless otherwise indicated.