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Título: | Transfer Hydrogenation of alfa-branched ketimines: Enantioselective Synthesis of Cycloalkyl Amines via Dynamic Kinetic Resolution |
Autor: | Ros, Abel CSIC ORCID CVN ; Magriz, Antonio CSIC; Hansjörg, Dietrick; Ford, Mark; Fernández, Rosario; Lassaletta, José M. CSIC ORCID | Palabras clave: | Amines Asymmetric catalysis Dynamic kinetic resolution Iridium Ruthenium Transfer hydrogenation |
Fecha de publicación: | 2005 | Editor: | Wiley-VCH | Citación: | Advanced Synthesis and Catalysis 347: 1917-1920 (2005) | Resumen: | The transfer hydrogenation of 2-substituted bicyclic and monocyclic ketimines using HCO2H/Et3N as the hydrogen source and TsDPEN-based Ru(II) and Ir(III) catalysts proceeds with dynamic kinetic resolution to afford the corresponding cis-cycloalkylamines with moderate to excellent levels of diastero- and enantioselectivity. A “one-pot” procedure starting from ketones as starting materials with in situ formation of the reacting imines has also been developed. | Descripción: | 4 páginas. | Versión del editor: | http://dx.doi.org/10.1002/adsc.200505291 | URI: | http://hdl.handle.net/10261/36065 | DOI: | 10.1002/adsc.200505291 | ISSN: | 1615-4150 |
Aparece en las colecciones: | (IIQ) Artículos |
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