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Title

Stereoselective Synthesis of Branched Cyclopentitols by Titanium(III)-Promoted Reductive Cyclization of 4-Oxiranylaldehydes and 4-Oxiranyl Ketones Derived from Hexoses

AuthorsChiara, José Luis ; Bobo, Sofía; Sesmillo, Esther
KeywordsCarbohydrates
Electron transfer
Epoxides
Radical reactions
Titanium
Issue Date2008
PublisherThieme
CitationSynthesis (19): 3160-3166 (2008)
AbstractTitanocene chloride efficiently promotes the intramolecular reductive cross coupling of highly functionalized 4-oxiranyl­aldehydes and 4-oxiranyl ketones derived from readily available hexoses affording branched cyclopentitols with good stereoselectivity.
Description7 páginas.
Publisher version (URL)http://dx.doi.org/10.1055/s-2008-1067257
URIhttp://hdl.handle.net/10261/31018
DOI10.1055/s-2008-1067257
ISSN0039-7881
Appears in Collections:(IQOG) Artículos
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