Por favor, use este identificador para citar o enlazar a este item:
http://hdl.handle.net/10261/271026
COMPARTIR / EXPORTAR:
SHARE CORE BASE | |
Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL | DATACITE | |
Título: | Clip-off Chemistry: Synthesis by Programmed Disassembly of Reticular Materials** |
Autor: | Yang, Yunhui CSIC ORCID; Broto-Ribas, Anna CSIC ORCID; Ortín-Rubio, Borja CSIC ORCID; Gándara, Fernando de la; Carné-Sánchez, Arnau CSIC ORCID; Guillerm, Vincent CSIC ORCID; Jurado, Sergio; Busqué, Félix; Juanhuix, Judith; Maspoch, Daniel CSIC ORCID | Fecha de publicación: | 21-ene-2022 | Editor: | John Wiley & Sons | Citación: | Angewandte Chemie - International Edition 61(4): e202111228 (2022) | Resumen: | Bond breaking is an essential process in chemical transformations and the ability of researchers to strategically dictate which bonds in a given system will be broken translates to greater synthetic control. Here, we report extending the concept of selective bond breaking to reticular materials in a new synthetic approach that we call Clip-off Chemistry. We show that bond-breaking in these structures can be controlled at the molecular level; is periodic, quantitative, and selective; is effective in reactions performed in either solid or liquid phases; and can occur in a single-crystal-to-single-crystal fashion involving the entire bulk precursor sample. We validate Clip-off Chemistry by synthesizing two topologically distinct 3D metal-organic frameworks (MOFs) from two reported 3D MOFs, and a metal-organic macrocycle from metal-organic polyhedra (MOP). Clip-off Chemistry opens the door to the programmed disassembly of reticular materials and thus to the design and synthesis of new molecules and materials. | Versión del editor: | http://doi.org/10.1002/anie.202111228 | URI: | http://hdl.handle.net/10261/271026 | DOI: | 10.1002/anie.202111228 | Identificadores: | doi: 10.1002/anie.202111228 issn: 1521-3773 |
Aparece en las colecciones: | (ICMM) Artículos (CIN2) Artículos |
Ficheros en este ítem:
Fichero | Descripción | Tamaño | Formato | |
---|---|---|---|---|
Clip-off_chemistry_synthesis.pdf | 2,31 MB | Adobe PDF | Visualizar/Abrir |
CORE Recommender
SCOPUSTM
Citations
9
checked on 16-abr-2024
WEB OF SCIENCETM
Citations
1
checked on 23-feb-2024
Page view(s)
55
checked on 23-abr-2024
Download(s)
88
checked on 23-abr-2024
Google ScholarTM
Check
Altmetric
Altmetric
Este item está licenciado bajo una Licencia Creative Commons