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Título: | Uncapped gold nanoparticles for the metallization of organic monolayers |
Autor: | Martín-Barreiro, Alba CSIC ORCID; Soto, Rogelio; Chiodini, Stefano CSIC ORCID; García-Serrano, Aitor CSIC ORCID; Martín, Santiago CSIC ORCID; Herrer, Lucía CSIC ORCID; Perez Murano, Francesc X. CSIC ORCID ; Low, Paul J.; Serrano, José Luis CSIC ORCID; Marcos, Susana de CSIC ORCID; Galbán, Javier CSIC ORCID; Cea, Pilar CSIC ORCID | Fecha de publicación: | 2021 | Editor: | Wiley-VCH | Citación: | Advanced Materials Interfaces 8(18): 2100876 (2021) | Resumen: | Deposition of the top-contact electrode to create large-area electrode | monolayer | electrode junctions represents a contemporary challenge to the integration of molecular electronic phenomena into device structures. Here, a top contact electrode is formed on top of an organic monolayer over a large area (cm2) by two simple, sequential self-assembly steps. Initial self-assembly of 4,4′-(1,4-phenylenebis(ethyne-2,1-diyl))dianiline onto gold-on-glass substrates gives high-quality monolayers. The exposed amine functionality is subsequently used to anchor uncapped gold nanoparticles deposited in a second self-assembly step. These uncapped gold nanoparticles are prepared by thermolysis of lipoic acid stabilized gold nanoclusters and contain gold oxide (≈9%) that provides stability in the absence of an organic capping ligand. This two-step procedure results in full coverage of the monolayer by the densely packed gold nanoparticles, which spontaneously condense to give a semi-continuous film. The electrical properties of these junctions are determined from I–V curves, revealing uniform electrical response and absence of metallic short-circuits or evidence of damage to the underlying molecular monolayer. These promising electrical characteristics suggest that the deposition of uncapped gold nanoparticles on suitably functionalized molecular monolayers provides a path for the fabrication of molecular electronic devices using simple methodologies. | Versión del editor: | https://doi.org/10.1002/admi.202100876 | URI: | http://hdl.handle.net/10261/266341 | DOI: | 10.1002/admi.202100876 | E-ISSN: | 2196-7350 |
Aparece en las colecciones: | (INMA) Artículos (IMB-CNM) Artículos |
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uncapped.pdf | 1,79 MB | Adobe PDF | Visualizar/Abrir |
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