Please use this identifier to cite or link to this item: http://hdl.handle.net/10261/22693
Share/Export:
logo share SHARE logo core CORE BASE
Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL | DATACITE
Title

The rotational Raman spectra and cross sections of H2O, D2O, and HDO

AuthorsAvila, Gustavo; Tejeda, Guzmán CSIC ORCID; Fernández Sánchez, José María CSIC ORCID ; Montero, Salvador CSIC ORCID
KeywordsWater
H2O
D2O
HDO
Raman spectrum
Polarizability
Issue Date16-Jun-2003
PublisherElsevier
CitationJournal of Molecular Spectroscopy 220 , 259–275 (2003)
AbstractWe report the experimental rotational Raman spectra of H2O, and of a mixture of D2O and HDO in the vapor phase at room temperature, and their interpretation in terms of rotational–vibrational energies, wavefunctions, and transition moments of the molecular polarizability. These transition moments are based on high-level ab initio calculations of the wavelength dependent polarizability surface, and on wavefunctions where the rotational–vibrational coupling is considered in detail. As a byproduct of this analysis several tables have been compiled including scattering strengths and assignments for individual rotational transitions of the three species. From these tables the rotational Raman spectra can be simulated over the range of temperatures up to 2000 K for H2O, and up to 300 K for D2O and HDO.
Description17 pages, 4 figures, 6 tables.
Publisher version (URL)http://dx.doi.org/10.1016/S0022-2852(03)00123-1
URIhttp://hdl.handle.net/10261/22693
DOI10.1016/S0022-2852(03)00123-1
Appears in Collections:(CFMAC-IEM) Artículos

Show full item record
Review this work

SCOPUSTM   
Citations

29
checked on May 22, 2022

WEB OF SCIENCETM
Citations

30
checked on May 25, 2022

Page view(s)

298
checked on May 28, 2022

Google ScholarTM

Check

Altmetric

Dimensions


WARNING: Items in Digital.CSIC are protected by copyright, with all rights reserved, unless otherwise indicated.