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Title

The microbiological transformation of some ent-13-epi-manoyl oxide diterpenes by Gibberelle fujikuroi

AuthorsFraga, Braulio M. CSIC; González, Pedro; Guillermo, Ricardo; Hernández, Melchor G.; Rovirosa, Juana
KeywordsGibberella fujikuroi
microbiological transformation
diterpenes
ent-13-epi-manoyl oxide derivatives
varol
varodiol
Issue Date1989
PublisherElsevier
CitationPhytochemistry 28(7): pp. 1851-1854 (1989)
AbstractIncubation of ent-19-hydroxy-13-epi-manoyl oxide with Gibberella fujikuroi afforded ent-12a,19-dihydroxy-13-epi-manoyl oxide and ent-7B,12a19-trihydroxy-13-epi-manoyl oxide, the first of which was transformed by chemical methods into varol (ent-12a-hydroxy-13-epi-manoyl oxide). The incubation of ent-3B-hydroxy-13-epi-manoyl oxide (ribenol) with the same fungus gave the 12B-hydroxy, the 11B-hydroxy and the 11B,12B-dihydroxy derivatives of ribenol, the first of which was identical with varodiol.
URIhttp://hdl.handle.net/10261/22087
ISSN0031-9422
Appears in Collections:(IPNA) Artículos




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