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The formation of an ent-6a, 7a-epoxykaurene of possible biosynthetic significance by Gibberella fujikuroi

AuthorsFraga, Braulio M. ; González, Antonio G.; González, Pedro; Hanson, James R.; Hernández, Melchor G.; Hitchcock, Peter B.
Issue Date1982
PublisherRoyal Society of Chemistry (UK)
CitationJournal of the Chemical Society. Chemical communications 0: pp. 311-312 (1982)
AbstractWhereas ent-kaur-6,16-diene affords 7-hydroxykaurenolide and ent-18-hydroxykaur-6,16-diene affords 7,18-dihydroxykaurenoide on incubation with Gibberella fujikuori, ent-6a,7a-epoxy-3B, 18-dihydroxy-kaur-18-ene, the structure of which was determined by X-ray crystallography was obtained from ent-3B 18-dihydroxykaur-6,16-diene.
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