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| Título: | The transformation of epicandicandiol into a Gibberellin A12 Isomer |
Autor: | Fraga, Braulio M. CSIC; Hernández, Melchor G.; Arráez, Jacinto D.; Luis, J. G. | Fecha de publicación: | 1994 | Editor: | Elsevier | Citación: | Tetrahedron 50(44): pp. 12643-12648 (1994) | Resumen: | Favorskii rearrangement of a chloro-lactone (7), obtained in two steps from the diterpene epicandicandiol (1), afflorded 9, which after hydrolysis led to the gibberellin A12 isomer 10. The stereochemistry of the affected centres has been established as 5$-H, 6$-H revising the previously assigned 5%-H, 6$-H. The structures of minor products obtained in the autoxidation of 7-oxo-ent-kaur-16-en-18-methyl ester and in the reduction of 7-oxo-ent-kaur-5,16-dien-18$6-olide have also been established. | URI: | http://hdl.handle.net/10261/21685 | ISSN: | 0040-4020 |
| Aparece en las colecciones: | (IPNA) Artículos |
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