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The biotransformation of the diterpene 2B-hydroxy-ent-13-epi-manoyl oxide by Gibberelle fujikuroi

AuthorsFraga, Braulio M. ; González, Pedro; Hernández, Melchor G.; Suárez, Sergio
KeywordsGibberella fujokuroi
2B-Hydroxy-ent-13-epi-manoyl oxide
Issue Date2003
CitationPhytochemistry 62: pp. 67-70 (2003)
AbstractIncubation of the diterpene 2B-hidroxy-ent-13-epi-manoyl oxide with Gibberella fujikuroi afforded in good yield 2B,6B-dihydroxy-ent-13-epi-manoyl oxide, 2B,12B-dihydroxy-ent-13-epi-manoyl oxide and 2B,20-dihydroxy-ent-13-epi-manoyl oxide, confirming that although ent-13-epi-manoyl oxide is a final metabolite of a biosynthetic branch in tyhis fungus, more polar derivatives of this compound can be transformed by this micro-organism.
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