Please use this identifier to cite or link to this item:
http://hdl.handle.net/10261/21565
Share/Export:
![]() ![]() |
|
Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL | DATACITE | |
Title: | Raman spectra of (He)N-Br2(X) clusters: The role of boson/fermion statistics in a quantum solvent |
Authors: | López Durán, David; Lara Castells, María Pilar de ; Delgado Barrio, Gerardo CSIC ORCID ; Villarreal, Pablo CSIC ORCID; Paola, C. Di.; Gianturco, Franco Antonio; Jellinek, J. | Keywords: | Quantum chemistry HF calculations Atomic clusters Helium Bromine Fermion systems |
Issue Date: | 15-Aug-2004 | Publisher: | American Institute of Physics | Citation: | Journal of Chemical Physics 121(7): 2975 (2004) | Abstract: | The aim of this paper is to elucidate the role played by the bosonic/fermionic character of N He atoms solvating a Br2(X) molecule. To this end, an adiabatic model in the molecular stretching coordinate is assumed and the ground energy levels of the complexes are searched by means of Hartree (or Hartree-Fock) Quantum Chemistry calculations for 4He (or 3He) solvent atoms. Simulations of vib-rotational Raman spectra point at the spin multiplicity as the main feature responsible for the drastic difference in the rotational structures of molecules embedded in boson or fermion helium drops as already observed by the experiments of Grebenev et al. [S. Grebenev, J. P. Toennies, and A. F. Vilesov, Science 279 (1998) 2083]. | Description: | 10 pages, 9 figures, 4 tables.-- PACS: 33.20.Fb; 36.40.Mr; 05.30.Jp; 05.30.Fk; 33.70.Jg; 31.70.Dk; 31.15.Ne; 33.20.Vq | Publisher version (URL): | http://dx.doi.org/10.1063/1.1769369 | URI: | http://hdl.handle.net/10261/21565 | DOI: | 10.1063/1.1769369 | ISSN: | 0021-9606 |
Appears in Collections: | (CFMAC-IFF) Artículos |
Files in This Item:
File | Description | Size | Format | |
---|---|---|---|---|
GetPDFServlet.pdf | 172,63 kB | Adobe PDF | ![]() View/Open |
Review this work
SCOPUSTM
Citations
26
checked on May 24, 2022
WEB OF SCIENCETM
Citations
28
checked on May 24, 2022
Page view(s)
338
checked on May 28, 2022
Download(s)
289
checked on May 28, 2022
Google ScholarTM
Check
Altmetric
Dimensions
WARNING: Items in Digital.CSIC are protected by copyright, with all rights reserved, unless otherwise indicated.