English   español  
Please use this identifier to cite or link to this item: http://hdl.handle.net/10261/200140
Share/Impact:
Statistics
logo share SHARE logo core CORE   Add this article to your Mendeley library MendeleyBASE

Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL
Exportar a otros formatos:

Title

A MOF@COF composite with enhanced uptake through interfacial pore generation

AuthorsGarzón-Tovar, Luis ; Pérez-Carvajal, Javier ; Yazdi, Amirali; Hernández-Muñoz, Jose; Tarazona, Pedro; Imaz, Inhar ; Zamora, Félix; Maspoch, Daniel
Issue Date2019
PublisherWiley-VCH
CitationAngewandte Chemie International Edition 58(28): 9512-9516 (2019)
AbstractHerein, we describe a new class of porous composites comprising metal–organic framework (MOF) crystals confined in single spherical matrices made of packed covalent‐organic framework (COF) nanocrystals. These MOF@COF composites are synthesized through a two‐step method of spray‐drying and subsequent amorphous (imine‐based polymer)‐to‐crystalline (imine‐based COF) transformation. This transformation around the MOF crystals generates micro‐ and mesopores at the MOF/COF interface that provide far superior porosity compared to that of the constituent MOF and COF components added together. We report that water sorption in these new pores occurs within the same pressure window as in the COF pores. Our new MOF@COF composites, with their additional pores at the MOF/COF interface, should have implications for the development of new composites.
Publisher version (URL)https://doi.org/10.1002/anie.201904766
URIhttp://hdl.handle.net/10261/200140
DOI10.1002/anie.201904766
ISSN1433-7851
E-ISSN1521-3773
Appears in Collections:(CIN2) Artículos
Files in This Item:
File Description SizeFormat 
accesoRestringido.pdf59,24 kBAdobe PDFThumbnail
View/Open
Show full item record
Review this work
 

Related articles:


WARNING: Items in Digital.CSIC are protected by copyright, with all rights reserved, unless otherwise indicated.