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dc.contributor.authorSuárez-García, Salvioes_ES
dc.contributor.authorAdarsh, Nayarassery N.es_ES
dc.contributor.authorMolnár, Gábores_ES
dc.contributor.authorBousseksou, Azzedinees_ES
dc.contributor.authorGarcía, Yannes_ES
dc.contributor.authorDîrtu, Marinela M.es_ES
dc.contributor.authorSaiz-Poseu, Javieres_ES
dc.contributor.authorRobles, Robertoes_ES
dc.contributor.authorOrdejón, Pabloes_ES
dc.contributor.authorRuiz Molina, Danieles_ES
dc.date.accessioned2020-02-06T11:00:54Z-
dc.date.available2020-02-06T11:00:54Z-
dc.date.issued2018-
dc.identifier.citationACS Applied Nano Materials 1(6): 2662-2668 (2018)es_ES
dc.identifier.issn2574-0970-
dc.identifier.urihttp://hdl.handle.net/10261/199855-
dc.description.abstractDevelopment of novel 2D materials with singular and thrilling properties has aroused large interest due to the novel unexpected applications that can be derived from there. In this sense, coordination polymers (CPs) have appeared as matching candidates thanks to their rational chemical design and the added-value properties given by the presence of metal ions. This is the case of switchable spin-crossover systems that have been proposed as excellent candidates for data storage or sensing, among others. Here we report the delamination of crystals of the 2D spin-crossover (SCO) {[Fe(L1)2](ClO4)2}∝ (1) CP by liquid-phase exfoliation (LPE) in water. The application of this top-down technique results in the formation of flakes with controlled thicknesses, down to 1–2 nm thick (mostly mono- and bilayer), that retain the chemical composition and SCO interconversion of the bulk material. Moreover, these flakes can be handled as stable colloidal dispersions for many days. This allows for a controlled transfer to solid substrates and the formation of thermochromic polymeric films as a proof-of-concept of device. These first results will definitely open new venues and opportunities for the investigation and future integration of these original switchable 2D materials in devices.es_ES
dc.description.sponsorshipThis work was supported by projects MAT2015-70615-R, CTQ2015-65439-R, and FIS2015-64886-C5-3-P from the Spanish Government funds and by European Regional Development Fund (ERDF). Funded by the CERCA Program/Generalitat de Catalunya. ICN2 is supported by the Severo Ochoa program from Spanish Ministry of Economy, Industry and Competitiveness (MINECO, Grant SEV-2013-0295). Funded by the project 2014-SGR-301 (Generalitat de Catalunya). This work was supported by the Fonds National de la Recherche Scientifique-FNRS (PDR T.0102.15) and COST actions CM1305 and CA15128. M. M. D is a chargé de recherches from the F.R.S.-FNRS. S.S.-G. acknowledges the support from MINECO BES-2015-071492 grant. R.R. and P.O. acknowledge support from EU H2020-EINFRA-5-2015 MaX Center of Excellence (Grant 676598).es_ES
dc.language.isoenges_ES
dc.publisherAmerican Chemical Societyes_ES
dc.relationinfo:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2015-70615-Res_ES
dc.relationinfo:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2015-65439-Res_ES
dc.relationinfo:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/FIS2015-64886-C5-3-Pes_ES
dc.relationinfo:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/SEV-2013-0295es_ES
dc.relationinfo:eu-repo/grantAgreement/EC/H2020/676598es_ES
dc.relation.isversionofPostprintes_ES
dc.rightsopenAccesses_ES
dc.subject2D coordination polymeres_ES
dc.subjectSpin crossoveres_ES
dc.subjectDelaminationes_ES
dc.subjectLiquid-phase exfoliationes_ES
dc.titleSpin-crossover in an exfoliated 2D coordination polymer and its implementation in thermochromic filmses_ES
dc.typeartículoes_ES
dc.identifier.doi10.1021/acsanm.8b00341-
dc.description.peerreviewedPeer reviewedes_ES
dc.relation.publisherversionhttps://doi.org/10.1021/acsanm.8b00341es_ES
dc.contributor.funderMinisterio de Economía y Competitividad (España)es_ES
dc.contributor.funderEuropean Commissiones_ES
dc.contributor.funderGeneralitat de Catalunyaes_ES
dc.contributor.funderMinisterio de Economía, Industria y Competitividad (España)es_ES
dc.contributor.funderFonds de la Recherche Scientifique (Fédération Wallonie-Bruxelles)es_ES
dc.relation.csices_ES
oprm.item.hasRevisionno ko 0 false*
dc.identifier.funderhttp://dx.doi.org/10.13039/501100000780es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100002809es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100010198es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100002661es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100003329es_ES
local.message.claim2022-03-07T12:59:23.567+0100|||rp14613|||submit_approve|||dc_contributor_author|||None*
dc.type.coarhttp://purl.org/coar/resource_type/c_6501es_ES
item.openairetypeartículo-
item.cerifentitytypePublications-
item.languageiso639-1en-
item.grantfulltextopen-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.fulltextWith Fulltext-
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