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Metal acetylacetonates as a source of metals for aqueous synthesis of metal–organic frameworks

AuthorsAvci-Camur, Civan ; Pérez-Carvajal, Javier ; Imaz, Inhar ; Maspoch, Daniel
KeywordsMetal−organic frameworks
Green synthesis
Issue Date2018
PublisherAmerican Chemical Society
CitationACS Sustainable Chemistry and Engineering 6(11): 14554-14560 (2018)
AbstractDemand continues for environmentally sound, high-yielding processes for the large-scale production of metal–organic frameworks (MOFs). Here we describe the use of metal acetylacetonate complexes as an alternative source of metals for the aqueous synthesis of MOFs. We have synthesized several carboxylate-based Zr(IV)-(UiO-66-NH2, Zr-fumarate, UiO-66-(OH)2, UiO-66-COOH and UiO-66-(COOH)2), Fe(III)-(MIL-88A) and Al(III)-(CAU-10) porous MOFs from their corresponding metal acetylacetonates in good yields (typically >85%) and, in some cases, at room temperature.
Publisher version (URL)https://doi.org/10.1021/acssuschemeng.8b03180
Appears in Collections:(CIN2) Artículos
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